Trinkwasser-Ringversuch 4/2009 - LANUV: Home · 4 Die Auswertung der Daten dieses Ringversuchs...

Trinkwasser-Ringversuch 4/2009

Im Auftrag des Ministeriums für Umwelt und Naturschutz, Landwirtschaft und Verbraucherschutz (MUNLV) NRW

und des Niedersächsischen Ministeriums für Soziales (MS)

- O 2 - LHKW/Benzol -

1,2-Dichlorethan, Benzol, Bromdichlormethan,

Dibromchlormethan, Tetrachlorethen, Tribrommethan, Trichlorethen, Trichlormethan

Februar 2010

2

Bei Rückfragen wenden Sie sich bitte an:

Landesamt für Natur, Umwelt und Verbraucherschutz

Nordrhein-Westfalen Postfach 10 10 52

45610 Recklinghausen

Referenzstelle Trinkwasser

Günter Grubert Tel.: 0211-1590 2 333

[email protected]

Jutta Eggersmann

Tel.: 0251-7793 116 [email protected]

2010

3

Auswertung

Parameter/Untersuchungsverfahren Im Rahmen dieses Ringversuches wurden die Untersuchungsparameter 1,2-Dichlorethan, Benzol, Bromdichlormethan, Dibromchlormethan, Tetrachlorethen, Tribrommethan, Trichlorethen, Trichlormethan angeboten. Als Untersuchungsverfahren sollte möglichst ein genormtes Verfahren gewählt werden.

Teilnehmerzahl Insgesamt haben 146 Labore an diesem Ringversuch teilgenommen. Die Anmeldung erfolgte für jeden Untersuchungsparameter separat.

Proben Die Ringversuchsproben wurden im IWW Rheinisch-Westfälischen Institut für Wasser-forschung, Mülheim a.d. Ruhr, durch Aufstocken von Trinkwasser mit Standards hergestellt. Es wurden 7 Chargen (A – G) mit unterschiedlichen Konzentrationsniveaus erstellt. Jeder Teilnehmer erhielt 3 unterschiedliche Proben, die jeweils alle oben aufgeführten Para-meter in messbaren Konzentrationen enthielten. Die Auswahl der Proben auf die Teilnehmer erfolgte zufällig. Die Beschriftung der Proben war für sämtliche Teilnehmer identisch (Probe I bis Probe III), wodurch der Möglichkeit eines unzulässigen Informationsaustausches unter den Teilnehmern vorgebeugt wurde.

Probenversand, Laufzeit Die Proben wurden am Montag, den 09. November 2009 mit dem Paketdienst DPD ver-schickt und bis 18:00 am Folgetag den Teilnehmern zugestellt. Die Abgabefrist für die Ergebnisse endete am 07. Dezember 2009, so dass die Bearbeitungs-zeit etwa 4 Wochen betrug. Die Ergebnisformulare waren per Post oder Telefax, die LAB-Datei per Email zu übermitteln.

Auswertung der Daten Obwohl durch die Art der Probenherstellung sowie die Verwendung hochreiner, zertifizierter Standards und Trinkwasser bei diesem Ringversuch die Vorgabewerte aller Parameter als konventionell richtige Werte angesehen werden könnten, beziehen sich die statistischen Aus-wertungen in diesem Ringversuch auf den Gesamtmittelwert der Labore und nicht auf den Vorgabewert, um einem möglichen Blindwert des Trinkwassers Rechnung zu tragen. Die mittleren Wiederfindungen der Gesamtmittelwerte sämtlicher Teilnehmer aus allen Char-gen zu den theoretischen Werten des Probenansatzes lagen in der Regel zwischen 94 % (Tri- und Tetrachlorethen) und 102 % (Trichlormethan). Ausgenommen davon war Tribrom-methan, das eine mittlere Wiederfindung von 88,9 % mit einer hohen Streuung der Wieder-findungsraten über die verschiedenen Niveaus aufwies.

4

Die Auswertung der Daten dieses Ringversuchs wurde mit der Auswertesoftware „ProLab“ der Fa. QuoData, Dresden, durchgeführt. Sie erfolgte nach DIN 38402 - A 45 „Ringversuche zur externen Qualitätskontrolle von Laboratorien“ mit Hilfe des kombinierten Schätzverfah-rens Hampel/Q-Methode, eines Verfahrens der robusten Statistik. Als Sollwert msoll wurde der Hampel-Schätzer verwendet. Die mit der Q-Methode berechne-ten Vergleichsstandardabweichungen sR wurden zunächst als Sollstandardabweichungen ssoll, die zur Bewertung der Einzelwerte herangezogen werden, festgelegt. Aus Sollwertwert msoll und Sollstandardabweichung ssoll wurde für jeden Messwert nach fol-gender Formel ein Z-Score berechnet:

( )

sollsMesswertScoreZ sollm−

=−

Dieser Z-Score wird mittels Korrekturfaktoren zu ZU-Scores modifiziert. Als Toleranzgrenze wird |ZU|=2 festgelegt.

Limitierung der Standardabweichung Um zu verhindern, dass die so ermittelten Toleranzgrenzen für die angewandte Untersu-chungsmethodik zu weit oder zu eng liegen, wurde für die Sollstandardabweichung für sämt-liche Parameter 5% als Untergrenze und 25% als Obergrenze festgelegt. Während die untere Limitierung bei keiner Proben-Parameter-Kombination zum Einsatz kam, wurde die obere Limitierung nur bei dem Parameter Benzol in der Charge F angewandt.

Erfolgskriterien für diesen Ringversuch Die Kriterien sind den Gegebenheiten der Trinkwasserverordnung 2001 angepasst und die Empfehlungen zur Ringversuchsdurchführung des UBA sind berücksichtigt:

• Bewertung der Messwerte durch Zu-Scores (Kriterium: akzeptabel: |Zu| ≤ 2)

• Einzelbewertung der Parameter, nicht des gesamten Ringversuchs (Kriterium: mehr als die Hälfte der Messwerte - 2 von 3 - eines Parameters müssen akzeptabel sein)

Von 146 Teilnehmern haben 104 (71,2%) die von ihnen untersuchten Parameter erfolgreich und 87 (59,6 %) sämtliche Parameter des Ringversuches erfolgreich bestimmt. Auf dem Zertifikat sind neben den verbindlich angemeldeten die Parameter aufgeführt, die erfolgreich bestimmt wurden. Sämtliche weiteren Ergebnisse sind den nachfolgenden Tabellen und Grafiken zu entnehmen.

Merkmal Sollwert Soll-STD.rel.Soll-STD.[%]

Vergleichs-STD

rel.Vergleichs-STD [%]

Tol. unten Tol. oben EinheitAnzahl Labore/Werte

1,2-Dichlorethan 12DCE 3,169 0,552 17,42 0,552 17,42 2,146 4,387 µg/l 55

Benzol BENZOL 0,970 0,234 24,14 0,234 24,14 0,545 1,509 µg/l 54

Bromdichlormethan BRDCLMET 8,790 0,919 10,46 0,919 10,46 7,038 10,735 µg/l 60

Dibromchlormethan DBRCLMET 7,829 0,858 10,95 0,858 10,95 6,198 9,649 µg/l 60

Tetrachlorethen TETETHEN 0,606 0,146 24,16 0,146 24,16 0,340 0,943 µg/l 60

Tribrommethan TRIBRMET 7,151 0,749 10,48 0,749 10,48 5,723 8,736 µg/l 60

Trichlormethan TRICLMET 3,821 0,526 13,76 0,526 13,76 2,833 4,955 µg/l 62

Trichlorethen TRIETHEN 4,052 0,616 15,20 0,616 15,20 2,901 5,393 µg/l 60

Ringversuchskenndaten Charge A

4/2009 O 2 - LHKW / Benzol

Übersicht Zu-Scores

AProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2

12DCE BENZOL BRDCLMET DBRCLMET TETETHEN TRIBRMET TRIETHEN TRICLMET11111

103103103103103103

104104104104104104104104105105105105105105105105

106106106106106106106106

107107107107107107107107108108108108108108108108

116116116116116116116116117117117117117117117117

118118118118118118118121121121121121121121121

124124124124124124124124126126126126126126126126

127127127127127127127127133133133133133133133133

134134134134134134134134

135135135135135135135135137137137137137137137137

140140140140140140140140142142142142142142142142

1471471471471471471471471515151515151515

16161616161616161717171717171717

2121212121212323232323232323

2525252525252525

27272727272727272828282828282828

2933333333

4,39

12,09 17,17

2,20

2,69

2,284,23

4,00

47,31

4,50

2,64

2,61

2,61

-2,28

-2,44

-8,42

-2,17-2,83

-4,10

-3,04

-3,79

-2,37

quo data



AProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


43434343434345454545454545455050505050505050525252525252525253535353535353535454545454545454

555555555555555656565656565656575757575757575758585858585858585959595959595959

60606060606060606161616161616161626262626262626263636363636363636464646464646464

6565656565656565676767676767676768686868686868687878787880808080808080808282828282828282

8585858585858585868686868686868687878787878787939393939393939398

2,35

2,86 2,30

3,049,37

5,14

2,06

2,40

2,813,77

2,31

4,32 10,17

24,47

-2,42

-2,26

-2,12

-2,27

-2,07-2,87

-2,17

-2,50

quo data


EinzeldarstellungProbe: Sollwert:

Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:

Rel.Vergleichs-STD (VR, rel):

Rel.Soll STD:

Vergleichs-STD (VR):

A

1,2-Dichlorethan

DIN 38402 A45

55

2,146 - 4,387 µg/l (|Zu-Score| < 2,00)

3,169 µg/l (empirischer Wert)

0,552 µg/l (Limited)

17,42% (Limited)

17,42%

0,552 µg/l

ProLab 2009

Labor

86 106

121 16 25 61 78 35 50 62 3

117

142 93 147

104 56 134 17 107 55 58 59 133 68 54 63 140

105 65 60 85 15 33 126 52 64 127

116 40 80 23 118 37 57 67 108 27 53 135

137 45 82 124 28

µg/l

11

10

9

8

7

6

5

4

3

2

1

0

Mittelw

ert

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

1,2-Dichlorethan

DIN 38402 A45

55

2,146 - 4,387 µg/l (|Zu-Score| < 2,00)



17,42% (Limited)

17,42%

0,552 µg/l

Laborcode GH STD Z-Score GH 1 GH 2 GH 3 GH 4

104 2,990 -0,350 2,990105 3,170 0,002 3,170106 2,000 -2,284 2,000107 3,050 -0,233 3,050108 3,760 0,970 3,760116 3,420 0,412 3,420117 2,850 -0,623 2,850118 3,590 0,691 3,590121 2,270 -1,757 2,270124 5,840 4,386 5,840126 3,330 0,264 3,330127 3,390 0,363 3,390133 3,100 -0,135 3,100134 3,010 -0,311 3,010135 4,031 1,415 4,031137 4,045 1,438 4,045140 3,150 -0,037 3,150142 2,900 -0,526 2,900147 2,960 -0,409 2,96015 3,310 0,231 3,31016 2,287 -1,724 2,28717 3,015 -0,301 3,01523 3,570 0,658 3,57025 2,380 -1,542 2,38027 3,930 1,249 3,93028 10,529 12,086 10,5293 2,800 -0,721 2,80033 3,310 0,231 3,31035 2,589 -1,133 2,58937 3,597 0,703 3,59740 3,430 0,428 3,43045 4,600 2,350 4,60050 2,710 -0,897 2,71052 3,330 0,264 3,33053 3,930 1,249 3,93054 3,140 -0,057 3,14055 3,060 -0,213 3,06056 3,000 -0,330 3,00057 3,600 0,708 3,60058 3,069 -0,196 3,06959 3,090 -0,155 3,09060 3,240 0,116 3,240


61 2,440 -1,425 2,44062 2,750 -0,819 2,75063 3,140 -0,057 3,14064 3,340 0,281 3,34065 3,187 0,029 3,18767 3,710 0,888 3,71068 3,130 -0,076 3,13078 2,520 -1,268 2,52080 3,527 0,588 3,52782 4,910 2,859 4,91085 3,280 0,182 3,28086 1,932 -2,417 1,93293 2,900 -0,526 2,900



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Benzol

DIN 38402 A45

54

0,545 - 1,509 µg/l (|Zu-Score| < 2,00)



24,14% (Limited)

24,14%

0,234 µg/l

ProLab 2009

Labor

45 80 133

106 16 3

121

105 25 50 93 63 127

142 61 58 134

140

117

107 33 65 59 56 108 37 68 60 147 29 54 15 23 64 126 53 135

116 62 40 52 104 67 1 27 85 57 124 17 137 82 86 87 28

µg/l

3,5

3

2,5

2

1,5

1

0,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Benzol

DIN 38402 A45

54

0,545 - 1,509 µg/l (|Zu-Score| < 2,00)



24,14% (Limited)

24,14%

0,234 µg/l


1 1,160 0,705 1,160104 1,120 0,557 1,120105 0,760 -0,988 0,760106 0,610 -1,695 0,610107 0,940 -0,139 0,940108 0,974 0,016 0,974116 1,060 0,335 1,060117 0,910 -0,281 0,910121 0,700 -1,271 0,700124 1,360 1,446 1,360126 1,050 0,298 1,050127 0,837 -0,625 0,837133 0,580 -1,837 0,580134 0,880 -0,422 0,880135 1,058 0,328 1,058137 1,382 1,528 1,382140 0,900 -0,328 0,900142 0,840 -0,611 0,840147 1,020 0,187 1,02015 1,040 0,261 1,04016 0,613 -1,681 0,61317 1,377 1,509 1,37723 1,040 0,261 1,04025 0,770 -0,941 0,77027 1,160 0,705 1,16028 5,605 17,171 5,60529 1,020 0,187 1,0203 0,650 -1,507 0,65033 0,940 -0,139 0,94037 0,984 0,053 0,98440 1,100 0,483 1,10045 0,490 -2,261 0,49050 0,790 -0,847 0,79052 1,110 0,520 1,11053 1,050 0,298 1,05054 1,020 0,187 1,02056 0,970 0,002 0,97057 1,300 1,224 1,30058 0,875 -0,446 0,87559 0,965 -0,022 0,96560 1,000 0,113 1,00061 0,840 -0,611 0,840


62 1,060 0,335 1,06063 0,832 -0,649 0,83264 1,040 0,261 1,04065 0,946 -0,111 0,94667 1,140 0,631 1,14068 0,990 0,076 0,99080 0,520 -2,120 0,52082 1,590 2,298 1,59085 1,170 0,742 1,17086 1,790 3,039 1,79087 3,500 9,374 3,50093 0,829 -0,663 0,829



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Bromdichlormethan

DIN 38402 A45

60

7,038 - 10,735 µg/l (|Zu-Score| < 2,00)



10,46% (Limited)

10,46%

0,919 µg/l

ProLab 2009

Labor

25 61 16 63 142 43 68 106 27 3 85 105 80 86 37 62 52 58 35 65 93 67 107 82 117 21 121

147

103 28 60 50 59 56 108 64 127 33 53 17 135

140 87 15 54 126 55 1

133 45 137

104

118

116

134 40 57 124 23 39

µg/l

14

13

12

11

10

9

8

7

6

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Bromdichlormethan

DIN 38402 A45

60

7,038 - 10,735 µg/l (|Zu-Score| < 2,00)



10,46% (Limited)

10,46%

0,919 µg/l


1 9,600 0,833 9,600103 8,800 0,010 8,800104 9,860 1,100 9,860105 8,180 -0,696 8,180106 7,640 -1,313 7,640107 8,610 -0,206 8,610108 9,000 0,216 9,000116 9,920 1,162 9,920117 8,630 -0,183 8,630118 9,890 1,131 9,890121 8,660 -0,148 8,660124 10,930 2,201 10,930126 9,360 0,586 9,360127 9,110 0,329 9,110133 9,600 0,833 9,600134 9,960 1,203 9,960135 9,149 0,369 9,149137 9,772 1,010 9,772140 9,200 0,422 9,200142 7,500 -1,473 7,500147 8,790 0,000 8,79015 9,210 0,432 9,21016 7,487 -1,488 7,48717 9,134 0,354 9,13421 8,630 -0,183 8,63023 11,410 2,694 11,41025 6,650 -2,443 6,65027 7,890 -1,027 7,89028 8,800 0,010 8,8003 7,980 -0,925 7,98033 9,110 0,329 9,11035 8,339 -0,515 8,33937 8,219 -0,652 8,21939 13,790 5,142 13,79040 9,990 1,234 9,99043 7,500 -1,473 7,50045 9,600 0,833 9,60050 8,920 0,134 8,92052 8,270 -0,594 8,27053 9,120 0,339 9,12054 9,220 0,442 9,22055 9,380 0,607 9,380


56 8,970 0,185 8,97057 10,790 2,057 10,79058 8,313 -0,545 8,31359 8,950 0,165 8,95060 8,850 0,062 8,85061 6,800 -2,272 6,80062 8,220 -0,651 8,22063 7,490 -1,484 7,49064 9,090 0,308 9,09065 8,356 -0,495 8,35667 8,570 -0,251 8,57068 7,570 -1,393 7,57080 8,211 -0,661 8,21182 8,620 -0,194 8,62085 8,100 -0,788 8,10086 8,212 -0,660 8,21287 9,200 0,422 9,20093 8,530 -0,297 8,530



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Dibromchlormethan

DIN 38402 A45

60

6,198 - 9,649 µg/l (|Zu-Score| < 2,00)



10,95% (Limited)

10,95%

0,858 µg/l

ProLab 2009

Labor

137 25 43 61 106

117 63 105

133

142

121 86 35 16 52 39 37 65 64 67 3 80 27 33 93 104 23 147

127 62 126 60 107 58 1 50 15 17 56 85 28 116 54 140

135 55 21 57 45 40 134 59 108

118

103 87 124 68 53 82

µg/l

11

10,5

10

9,5

9

8,5

8

7,5

7

6,5

6

5,5

5

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Dibromchlormethan

DIN 38402 A45

60

6,198 - 9,649 µg/l (|Zu-Score| < 2,00)



10,95% (Limited)

10,95%

0,858 µg/l


1 7,900 0,078 7,900103 8,900 1,177 8,900104 7,660 -0,207 7,660105 6,900 -1,139 6,900106 6,660 -1,433 6,660107 7,870 0,045 7,870108 8,740 1,001 8,740116 8,190 0,397 8,190117 6,800 -1,262 6,800118 8,810 1,078 8,810121 6,990 -1,029 6,990124 9,180 1,485 9,180126 7,790 -0,048 7,790127 7,720 -0,134 7,720133 6,900 -1,139 6,900134 8,700 0,957 8,700135 8,318 0,538 8,318137 0,958 -8,425 0,958140 8,200 0,408 8,200142 6,900 -1,139 6,900147 7,690 -0,170 7,69015 7,950 0,133 7,95016 7,207 -0,763 7,20717 8,047 0,240 8,04721 8,370 0,595 8,37023 7,670 -0,195 7,67025 6,060 -2,169 6,06027 7,610 -0,268 7,61028 8,180 0,386 8,1803 7,530 -0,367 7,53033 7,620 -0,256 7,62035 7,179 -0,797 7,17937 7,321 -0,623 7,32139 7,250 -0,710 7,25040 8,530 0,771 8,53043 6,200 -1,997 6,20045 8,500 0,738 8,50050 7,910 0,089 7,91052 7,210 -0,759 7,21053 9,530 1,870 9,53054 8,190 0,397 8,19055 8,360 0,584 8,360


56 8,170 0,375 8,17057 8,460 0,694 8,46058 7,871 0,046 7,87159 8,710 0,968 8,71060 7,840 0,012 7,84061 6,340 -1,826 6,34062 7,780 -0,060 7,78063 6,870 -1,176 6,87064 7,470 -0,440 7,47065 7,355 -0,581 7,35567 7,470 -0,440 7,47068 9,260 1,573 9,26080 7,567 -0,321 7,56782 10,010 2,397 10,01085 8,170 0,375 8,17086 7,083 -0,915 7,08387 9,100 1,397 9,10093 7,630 -0,244 7,630



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Tetrachlorethen

DIN 38402 A45

60

0,340 - 0,943 µg/l (|Zu-Score| < 2,00)



24,16% (Limited)

24,16%

0,146 µg/l

ProLab 2009

Labor

27 16 78 25 106 3 33 64 28 80 117

140

142 61 86 147 93 56 55 59 58 127 43 50 62 105

135

107

121

126 65 45 116 60 39 54 108 52 82 37 67 17 85 87 35 23 40 15 63 57 118 21 68 124

133

103 53 134

104

137

µg/l

1,51,41,31,21,1

10,90,8

0,70,60,50,40,30,20,1

0

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Tetrachlorethen

DIN 38402 A45

60

0,340 - 0,943 µg/l (|Zu-Score| < 2,00)



24,16% (Limited)

24,16%

0,146 µg/l


103 0,990 2,277 0,990104 1,320 4,232 1,320105 0,585 -0,156 0,585106 0,430 -1,325 0,430107 0,590 -0,118 0,590108 0,622 0,097 0,622116 0,610 0,026 0,610117 0,500 -0,797 0,500118 0,800 1,151 0,800121 0,590 -0,118 0,590124 0,840 1,388 0,840126 0,590 -0,118 0,590127 0,568 -0,284 0,568133 0,940 1,981 0,940134 1,280 3,995 1,280135 0,585 -0,156 0,585137 8,591 47,310 8,591140 0,500 -0,797 0,500142 0,520 -0,646 0,520147 0,530 -0,571 0,53015 0,740 0,796 0,74016 0,377 -1,725 0,37717 0,682 0,452 0,68221 0,830 1,329 0,83023 0,716 0,654 0,71625 0,420 -1,400 0,42027 0,230 -2,833 0,23028 0,475 -0,985 0,4753 0,430 -1,325 0,43033 0,470 -1,023 0,47035 0,705 0,589 0,70537 0,653 0,281 0,65339 0,620 0,085 0,62040 0,720 0,677 0,72043 0,570 -0,269 0,57045 0,600 -0,043 0,60050 0,580 -0,193 0,58052 0,650 0,263 0,65053 1,080 2,810 1,08054 0,620 0,085 0,62055 0,552 -0,405 0,55256 0,550 -0,420 0,550


57 0,760 0,914 0,76058 0,558 -0,359 0,55859 0,552 -0,405 0,55260 0,610 0,026 0,61061 0,520 -0,646 0,52062 0,580 -0,193 0,58063 0,740 0,796 0,74064 0,470 -1,023 0,47065 0,590 -0,118 0,59067 0,675 0,411 0,67568 0,830 1,329 0,83078 0,380 -1,702 0,38080 0,493 -0,850 0,49382 0,650 0,263 0,65085 0,700 0,559 0,70086 0,529 -0,578 0,52987 0,700 0,559 0,70093 0,548 -0,435 0,548



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Tribrommethan

DIN 38402 A45

60

5,723 - 8,736 µg/l (|Zu-Score| < 2,00)



10,48% (Limited)

10,48%

0,749 µg/l

ProLab 2009

Labor

87 86 63 61 43 68 39 25 104

121 33 27 126 64 35 142 65 93 60 55 67 117 58 62 52 37 50 105

140 82 127 16 134

116 15 56 85 40 1 28 57 147 21 108

107

135

133 80 53 137 17 3

103 45 124

118 59 23 54 106

µg/l

11

10,5

10

9,5

9

8,5

8

7,5

7

6,5

6

5,5

5

4,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Tribrommethan

DIN 38402 A45

60

5,723 - 8,736 µg/l (|Zu-Score| < 2,00)



10,48% (Limited)

10,48%

0,749 µg/l


1 7,500 0,441 7,500103 8,100 1,198 8,100104 6,450 -0,982 6,450105 7,190 0,050 7,190106 10,720 4,504 10,720107 7,620 0,592 7,620108 7,550 0,504 7,550116 7,280 0,163 7,280117 7,020 -0,183 7,020118 8,310 1,463 8,310121 6,470 -0,954 6,470124 8,260 1,400 8,260126 6,690 -0,645 6,690127 7,220 0,088 7,220133 7,700 0,693 7,700134 7,270 0,151 7,270135 7,624 0,597 7,624137 7,766 0,776 7,766140 7,200 0,062 7,200142 6,700 -0,631 6,700147 7,530 0,479 7,53015 7,280 0,163 7,28016 7,240 0,113 7,24017 7,839 0,869 7,83921 7,540 0,491 7,54023 9,240 2,636 9,24025 6,070 -1,514 6,07027 6,570 -0,813 6,57028 7,505 0,447 7,5053 8,030 1,110 8,03033 6,500 -0,912 6,50035 6,697 -0,636 6,69737 7,080 -0,099 7,08039 6,050 -1,542 6,05040 7,420 0,340 7,42043 5,900 -1,752 5,90045 8,100 1,198 8,10050 7,080 -0,099 7,08052 7,060 -0,127 7,06053 7,760 0,769 7,76054 10,140 3,772 10,14055 6,980 -0,239 6,980


56 7,330 0,226 7,33057 7,520 0,466 7,52058 7,041 -0,154 7,04159 8,980 2,308 8,98060 6,910 -0,337 6,91061 5,870 -1,794 5,87062 7,050 -0,141 7,05063 5,860 -1,808 5,86064 6,690 -0,645 6,69065 6,755 -0,554 6,75567 7,010 -0,197 7,01068 6,010 -1,598 6,01080 7,713 0,710 7,71382 7,210 0,075 7,21085 7,330 0,226 7,33086 5,672 -2,072 5,67287 5,100 -2,873 5,10093 6,870 -0,393 6,870



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Trichlorethen

DIN 38402 A45

60

2,901 - 5,393 µg/l (|Zu-Score| < 2,00)



15,20% (Limited)

15,20%

0,616 µg/l

ProLab 2009

Labor

106

142 16 68 63 61 64 25 43 93 86 33 108 87 147

127

121 58 117 62 80 82 105 27 52 39 65 134 15 50 135 3 67 107 54 140 35 126 60 17 116 45 56 40 55 59 37 53 28 104 23 85 21 133

118

137 57 103

124 78

µg/l

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

1

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Trichlorethen

DIN 38402 A45

60

2,901 - 5,393 µg/l (|Zu-Score| < 2,00)



15,20% (Limited)

15,20%

0,616 µg/l


103 5,800 2,608 5,800104 4,520 0,698 4,520105 3,910 -0,247 3,910106 1,690 -4,102 1,690107 4,050 -0,004 4,050108 3,650 -0,699 3,650116 4,280 0,340 4,280117 3,840 -0,369 3,840118 5,030 1,459 5,030121 3,780 -0,473 3,780124 5,800 2,608 5,800126 4,270 0,325 4,270127 3,760 -0,508 3,760133 5,000 1,414 5,000134 3,950 -0,178 3,950135 3,961 -0,159 3,961137 5,246 1,781 5,246140 4,200 0,220 4,200142 2,300 -3,043 2,300147 3,750 -0,525 3,75015 3,960 -0,160 3,96016 2,913 -1,978 2,91317 4,271 0,326 4,27121 4,960 1,354 4,96023 4,520 0,698 4,52025 3,290 -1,324 3,29027 3,930 -0,212 3,93028 4,447 0,589 4,4473 4,030 -0,039 4,03033 3,580 -0,820 3,58035 4,230 0,265 4,23037 4,416 0,543 4,41639 3,940 -0,195 3,94040 4,360 0,459 4,36043 3,500 -0,959 3,50045 4,300 0,370 4,30050 3,960 -0,160 3,96052 3,930 -0,212 3,93053 4,420 0,549 4,42054 4,150 0,146 4,15055 4,390 0,504 4,39056 4,330 0,414 4,330


57 5,330 1,906 5,33058 3,810 -0,421 3,81059 4,410 0,534 4,41060 4,270 0,325 4,27061 3,180 -1,515 3,18062 3,860 -0,334 3,86063 3,030 -1,775 3,03064 3,270 -1,358 3,27065 3,944 -0,188 3,94467 4,030 -0,039 4,03068 3,000 -1,827 3,00078 6,950 4,323 6,95080 3,867 -0,322 3,86782 3,870 -0,317 3,87085 4,950 1,339 4,95086 3,575 -0,829 3,57587 3,700 -0,612 3,70093 3,500 -0,959 3,500



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Trichlormethan

DIN 38402 A45

62

2,833 - 4,955 µg/l (|Zu-Score| < 2,00)



13,76% (Limited)

13,76%

0,526 µg/l

ProLab 2009

Labor

118 86 3 61 16 25 142

106 43 117 58 68 27 105

127

147 63 93 121

108 39 54 35 62 134 50 37 80 56 107 60 52 15 64 17 1

133

140 65 33 59 67 126 85 135 87 53 55 45 82 116 40 124

103

104 23 21 57 28 137 78 98

µg/l

5,5

5

4,5

4

3,5

3

2,5

2

1,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


A

Trichlormethan

DIN 38402 A45

62

2,833 - 4,955 µg/l (|Zu-Score| < 2,00)



13,76% (Limited)

13,76%

0,526 µg/l


1 3,900 0,139 3,900103 4,500 1,197 4,500104 4,570 1,320 4,570105 3,510 -0,630 3,510106 3,240 -1,176 3,240107 3,810 -0,023 3,810108 3,580 -0,488 3,580116 4,320 0,879 4,320117 3,440 -0,771 3,440118 1,950 -3,786 1,950121 3,560 -0,529 3,560124 4,420 1,056 4,420126 4,030 0,368 4,030127 3,520 -0,610 3,520133 3,900 0,139 3,900134 3,740 -0,165 3,740135 4,071 0,440 4,071137 4,839 1,795 4,839140 3,900 0,139 3,900142 3,200 -1,257 3,200147 3,520 -0,610 3,52015 3,850 0,051 3,85016 2,950 -1,763 2,95017 3,873 0,091 3,87321 4,670 1,497 4,67023 4,630 1,426 4,63025 3,160 -1,338 3,16027 3,490 -0,670 3,49028 4,740 1,620 4,7403 2,650 -2,370 2,65033 3,950 0,227 3,95035 3,681 -0,284 3,68137 3,763 -0,118 3,76339 3,590 -0,468 3,59040 4,360 0,950 4,36043 3,400 -0,852 3,40045 4,200 0,668 4,20050 3,740 -0,165 3,74052 3,830 0,015 3,83053 4,120 0,527 4,12054 3,590 -0,468 3,59055 4,130 0,544 4,130


56 3,800 -0,043 3,80057 4,720 1,585 4,72058 3,461 -0,729 3,46159 3,960 0,245 3,96060 3,820 -0,003 3,82061 2,750 -2,167 2,75062 3,700 -0,245 3,70063 3,550 -0,549 3,55064 3,870 0,086 3,87065 3,903 0,144 3,90367 3,990 0,297 3,99068 3,480 -0,691 3,48078 9,590 10,172 9,59080 3,790 -0,063 3,79082 4,310 0,862 4,31085 4,030 0,368 4,03086 2,585 -2,501 2,58587 4,100 0,491 4,10093 3,550 -0,549 3,55098 17,700 24,474 17,700


Vergleichs-STD


Tol. Unten Tol. oben EinheitAnzahl Labore/Werte









Ringversuchskenndaten Charge B



BProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


103103103103103103

104104104104104104104104106106106106106106106

107107107107107107107107

108108108108108108108108109109109109109109109109

1111111111111111116116116116116116116116

117117117117117117117117118118118118118118118

1212121212121212120120120120120120120120

121121121121121121121121122122122122122122122122

123123123123123123123123

124124124124124124124124125125125125125125125125

13131313131313131414141414141414

140140140140140140140140142142142142142142142142

147147147147147147147147149149149149149149149149

18181818181818181919191919191919

2222222

222222222222222424242424242424

26262626262626263030303030303030

6,353,43

3,25

3,40

3,24

2,12

2,35

2,02

2,362,31

2,78

2,24

2,32

2,123,36

-2,46

-2,27

-2,47

-3,15

-2,19

-4,04

-3,26

-2,02

-3,16

-4,43

-3,08

quo data



BProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


4444444441414141414142424242424242424444444444444444474747474747474748484848484848

494949494949494955555555

515151515151515152525252525252525353535353535353

54545454545454545656565656565656595959595959595966666666

6464646464646464

656565656565656577777777

7878787888888888

808080808080808087878787878787

88888888888888888989898989899999999

94949494949494949999999999999999

3,13 3,16

6,88

3,40

2,69

2,56

2,04

3,05

2,20

2,36

2,173,34

3,74

2,19

4,27

29,56

2,27

3,38

8,57

3,24

-2,72

-2,20

-2,24

-2,87

quo data



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

1,2-Dichlorethan

DIN 38402 A45

59

1,886 - 3,743 µg/l (|Zu-Score| < 2,00)



16,72% (Limited)

16,72%

0,458 µg/l

ProLab 2009

Labor

44 18 106 14 59 49 123

120

118 2 8 88 117 78 147 56 142 32 38 10 7

121 99 26 36 31 65 107 12 140 13 104

116 5 54 19 80 4 47 34 64 11 122 52 22 42 94 149

109 9

108 6 30 53 48 51 24 125

124

µg/l

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

1

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

1,2-Dichlorethan

DIN 38402 A45

59

1,886 - 3,743 µg/l (|Zu-Score| < 2,00)



16,72% (Limited)

16,72%

0,458 µg/l


10 2,530 -0,487 2,530104 2,760 0,046 2,760106 1,940 -1,873 1,940107 2,690 -0,111 2,690108 3,360 1,239 3,360109 3,300 1,119 3,30011 2,980 0,483 2,980116 2,780 0,085 2,780117 2,450 -0,675 2,450118 2,370 -0,863 2,37012 2,700 -0,087 2,700120 2,368 -0,867 2,368121 2,600 -0,322 2,600122 2,980 0,483 2,980123 2,340 -0,933 2,340124 5,930 6,350 5,930125 4,460 3,426 4,46013 2,740 0,006 2,74014 2,030 -1,662 2,030140 2,700 -0,087 2,700142 2,500 -0,557 2,500147 2,480 -0,604 2,480149 3,280 1,080 3,28018 1,690 -2,461 1,69019 2,830 0,185 2,8302 2,400 -0,792 2,40022 3,000 0,523 3,00024 4,370 3,247 4,37026 2,643 -0,221 2,64330 3,580 1,676 3,58031 2,659 -0,184 2,65932 2,500 -0,557 2,50034 2,920 0,364 2,92036 2,650 -0,205 2,65038 2,504 -0,548 2,5044 2,860 0,244 2,86042 3,010 0,543 3,01044 1,580 -2,719 1,58047 2,900 0,324 2,90048 3,645 1,806 3,64549 2,270 -1,098 2,2705 2,780 0,085 2,780


51 4,310 3,128 4,31052 2,980 0,483 2,98053 3,590 1,696 3,59054 2,810 0,145 2,81056 2,490 -0,581 2,49059 2,060 -1,591 2,0606 3,540 1,597 3,54064 2,960 0,443 2,96065 2,685 -0,122 2,6857 2,550 -0,440 2,55078 2,450 -0,675 2,4508 2,400 -0,792 2,40080 2,850 0,225 2,85088 2,410 -0,769 2,4109 3,300 1,119 3,30094 3,014 0,551 3,01499 2,600 -0,322 2,600



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Benzol

DIN 38402 A45

54

2,306 - 4,712 µg/l (|Zu-Score| < 2,00)



17,41% (Limited)

17,41%

0,593 µg/l

ProLab 2009

Labor

106 18 80 14 120

121 49 125

142

123 8

122 36 44 108

107 4

117 32 26 38 31 109 59 140 47 65 19 53 7 99 56 12 52 54 11 147 34 64 104 5 88 116 24 10 6 30 94 42 149 51 13 124 87

µg/l

8

7,5

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Benzol

DIN 38402 A45

54

2,306 - 4,712 µg/l (|Zu-Score| < 2,00)



17,41% (Limited)

17,41%

0,593 µg/l


10 3,950 0,834 3,950104 3,720 0,482 3,720106 2,160 -2,265 2,160107 3,150 -0,463 3,150108 3,140 -0,482 3,140109 3,280 -0,227 3,28011 3,580 0,268 3,580116 3,850 0,681 3,850117 3,190 -0,391 3,19012 3,530 0,192 3,530120 2,783 -1,131 2,783121 2,820 -1,064 2,820122 3,020 -0,700 3,020123 2,940 -0,846 2,940124 5,630 3,404 5,630125 2,890 -0,937 2,89013 5,520 3,235 5,52014 2,670 -1,337 2,670140 3,350 -0,100 3,350142 2,900 -0,918 2,900147 3,660 0,391 3,660149 4,790 2,119 4,79018 2,470 -1,701 2,47019 3,420 0,023 3,42024 3,940 0,819 3,94026 3,205 -0,363 3,20530 4,210 1,232 4,21031 3,263 -0,258 3,26332 3,200 -0,372 3,20034 3,660 0,391 3,66036 3,070 -0,609 3,07038 3,249 -0,283 3,2494 3,150 -0,463 3,15042 4,500 1,675 4,50044 3,090 -0,573 3,09047 3,400 -0,009 3,40049 2,840 -1,028 2,8405 3,740 0,513 3,74051 5,470 3,159 5,47052 3,550 0,222 3,55053 3,440 0,054 3,44054 3,550 0,222 3,550


56 3,510 0,161 3,51059 3,290 -0,209 3,2906 4,120 1,094 4,12064 3,670 0,406 3,67065 3,402 -0,005 3,4027 3,490 0,130 3,4908 3,000 -0,736 3,00080 2,474 -1,694 2,47487 7,900 6,876 7,90088 3,830 0,651 3,83094 4,436 1,577 4,43699 3,500 0,146 3,500



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Bromdichlormethan

DIN 38402 A45

62

6,054 - 9,230 µg/l (|Zu-Score| < 2,00)



10,45% (Limited)

10,45%

0,790 µg/l

ProLab 2009

Labor

18 14 48 142

120

106 65 2

122

123 26 80 89 10 121 38 32 88 99 7 36 49 47 117

107 5

147 54 19 149 34 4 31 13 56 103 22 24 59 64 53 52 8

140

116 11 6

108

118 12 44 125

109 94 104 42 87 9 30 124 51 41

µg/l

11

10,5

10

9,5

9

8,5

8

7,5

7

6,5

6

5,5

5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Bromdichlormethan

DIN 38402 A45

62

6,054 - 9,230 µg/l (|Zu-Score| < 2,00)



10,45% (Limited)

10,45%

0,790 µg/l


10 7,050 -0,677 7,050103 7,600 0,049 7,600104 8,620 1,270 8,620106 6,620 -1,248 6,620107 7,360 -0,265 7,360108 8,080 0,623 8,080109 8,530 1,162 8,53011 7,940 0,456 7,940116 7,880 0,384 7,880117 7,320 -0,318 7,320118 8,080 0,623 8,08012 8,150 0,707 8,150120 6,460 -1,461 6,460121 7,050 -0,677 7,050122 6,810 -0,996 6,810123 6,840 -0,956 6,840124 9,520 2,347 9,520125 8,320 0,910 8,32013 7,590 0,037 7,59014 5,700 -2,471 5,700140 7,850 0,348 7,850142 6,200 -1,806 6,200147 7,450 -0,145 7,450149 7,540 -0,026 7,54018 5,190 -3,148 5,19019 7,520 -0,052 7,5202 6,800 -1,009 6,80022 7,600 0,049 7,60024 7,610 0,061 7,61026 6,883 -0,899 6,88330 9,250 2,024 9,25031 7,584 0,029 7,58432 7,100 -0,610 7,10034 7,560 0,001 7,56036 7,240 -0,424 7,24038 7,054 -0,672 7,0544 7,560 0,001 7,56041 10,400 3,400 10,40042 8,950 1,665 8,95044 8,210 0,779 8,21047 7,300 -0,345 7,30048 5,900 -2,205 5,900


49 7,290 -0,358 7,2905 7,370 -0,252 7,37051 9,810 2,694 9,81052 7,790 0,276 7,79053 7,760 0,240 7,76054 7,480 -0,105 7,48056 7,590 0,037 7,59059 7,660 0,120 7,6606 8,070 0,611 8,07064 7,730 0,204 7,73065 6,624 -1,243 6,6247 7,210 -0,464 7,2108 7,800 0,288 7,80080 6,917 -0,854 6,91787 9,100 1,844 9,10088 7,200 -0,478 7,20089 7,000 -0,743 7,0009 9,150 1,904 9,15094 8,594 1,238 8,59499 7,200 -0,478 7,200



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Dibromchlormethan

DIN 38402 A45

62

4,140 - 6,616 µg/l (|Zu-Score| < 2,00)



11,59% (Limited)

11,59%

0,615 µg/l

ProLab 2009

Labor

18 89 14 121

106

117 26 123 80 2 48 120 32 99 64 122 38 65 142 19 7

147 4 47 116 49 13 24 5 11 52 34 140 8 88 104

107

118

149 54 6 12 56 22 36 44 31 42 10 59 125

109 9 94 108

124

103 53 30 51 41 87

µg/l

8

7,5

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

Mittelw

ert

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Dibromchlormethan

DIN 38402 A45

62

4,140 - 6,616 µg/l (|Zu-Score| < 2,00)



11,59% (Limited)

11,59%

0,615 µg/l


10 5,790 0,739 5,790103 6,200 1,365 6,200104 5,340 0,052 5,340106 4,400 -1,554 4,400107 5,380 0,113 5,380108 6,100 1,212 6,100109 5,940 0,968 5,94011 5,230 -0,130 5,230116 5,120 -0,319 5,120117 4,480 -1,416 4,480118 5,400 0,143 5,40012 5,480 0,266 5,480120 4,882 -0,727 4,882121 4,370 -1,605 4,370122 4,940 -0,628 4,940123 4,660 -1,108 4,660124 6,160 1,304 6,160125 5,830 0,800 5,83013 5,190 -0,199 5,19014 4,030 -2,188 4,030140 5,300 -0,010 5,300142 5,000 -0,525 5,000147 5,080 -0,388 5,080149 5,400 0,143 5,40018 2,950 -4,040 2,95019 5,050 -0,439 5,0502 4,700 -1,039 4,70022 5,550 0,373 5,55024 5,200 -0,182 5,20026 4,632 -1,156 4,63230 6,510 1,839 6,51031 5,700 0,602 5,70032 4,900 -0,696 4,90034 5,260 -0,079 5,26036 5,570 0,403 5,57038 4,947 -0,616 4,9474 5,080 -0,388 5,08041 6,980 2,556 6,98042 5,700 0,602 5,70044 5,640 0,510 5,64047 5,100 -0,353 5,10048 4,765 -0,928 4,765


49 5,180 -0,216 5,1805 5,210 -0,165 5,21051 6,640 2,037 6,64052 5,250 -0,096 5,25053 6,240 1,426 6,24054 5,410 0,159 5,41056 5,480 0,266 5,48059 5,790 0,739 5,7906 5,420 0,174 5,42064 4,910 -0,679 4,91065 4,992 -0,539 4,9927 5,060 -0,422 5,0608 5,300 -0,010 5,30080 4,683 -1,068 4,68387 7,300 3,045 7,30088 5,320 0,021 5,32089 4,000 -2,240 4,0009 5,950 0,983 5,95094 5,987 1,040 5,98799 4,900 -0,696 4,900



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Tetrachlorethen

DIN 38402 A45

63

1,456 - 3,045 µg/l (|Zu-Score| < 2,00)



17,93% (Limited)

17,93%

0,391 µg/l

ProLab 2009

Labor

109 78 18 106 14 80 7

120

142 64 2

122

108 89 10 59 4 49 38 26 121 31 147 65 123

149 19 107 44 88 116 6

140 32 8 54 117

125 36 5 48 12 56 99 13 24 22 47 11 34 53 118 30 52 87 42 124 9 41 104

103 51 94

µg/l

4

3,5

3

2,5

2

1,5

1

0,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Tetrachlorethen

DIN 38402 A45

63

1,456 - 3,045 µg/l (|Zu-Score| < 2,00)



17,93% (Limited)

17,93%

0,391 µg/l


10 1,950 -0,635 1,950103 3,200 2,359 3,200104 3,180 2,313 3,180106 1,510 -1,851 1,510107 2,120 -0,165 2,120108 1,900 -0,773 1,900109 1,000 -3,262 1,00011 2,410 0,533 2,410116 2,180 0,001 2,180117 2,270 0,209 2,270118 2,570 0,903 2,57012 2,300 0,279 2,300120 1,776 -1,116 1,776121 2,010 -0,469 2,010122 1,890 -0,801 1,890123 2,050 -0,358 2,050124 2,930 1,735 2,930125 2,270 0,209 2,27013 2,320 0,325 2,32014 1,520 -1,824 1,520140 2,200 0,047 2,200142 1,800 -1,049 1,800147 2,020 -0,441 2,020149 2,090 -0,247 2,09018 1,450 -2,017 1,45019 2,110 -0,192 2,1102 1,860 -0,883 1,86022 2,370 0,440 2,37024 2,340 0,371 2,34026 2,005 -0,483 2,00530 2,570 0,903 2,57031 2,013 -0,460 2,01332 2,200 0,047 2,20034 2,430 0,579 2,43036 2,270 0,209 2,27038 2,003 -0,488 2,0034 1,970 -0,579 1,97041 3,130 2,198 3,13042 2,700 1,203 2,70044 2,150 -0,082 2,15047 2,400 0,510 2,40048 2,290 0,255 2,290


49 1,990 -0,524 1,9905 2,280 0,232 2,28051 3,200 2,359 3,20052 2,580 0,926 2,58053 2,490 0,718 2,49054 2,250 0,163 2,25056 2,300 0,279 2,30059 1,950 -0,635 1,9506 2,180 0,001 2,18064 1,830 -0,966 1,83065 2,049 -0,361 2,0497 1,750 -1,188 1,75078 1,140 -2,874 1,1408 2,200 0,047 2,20080 1,620 -1,547 1,62087 2,600 0,972 2,60088 2,170 -0,026 2,17089 1,900 -0,773 1,9009 3,120 2,174 3,12094 3,623 3,337 3,62399 2,300 0,279 2,300



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Tribrommethan

DIN 38402 A45

61

0,355 - 0,885 µg/l (|Zu-Score| < 2,00)



21,89% (Limited)

21,89%

0,129 µg/l

ProLab 2009

Labor

117

109

116 64 120

103 18 122 11 104 14 123 10 140 89 32 88 147

121 49 80 4 26 118 38 36 24 47 8 99 22 65 56 6 2 34 13 48 51 12 54 44 31 59 7

107 5 52 149 94 124 41 42 87 30 125

142 9 19 108 53

µg/l

1,2

1,1

1

0,9

0,8

0,7

0,6

0,5

0,4

0,3

0,2

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Tribrommethan

DIN 38402 A45

61

0,355 - 0,885 µg/l (|Zu-Score| < 2,00)



21,89% (Limited)

21,89%

0,129 µg/l


10 0,500 -0,771 0,500103 0,440 -1,279 0,440104 0,470 -1,025 0,470106107 0,690 0,673 0,690108 1,000 2,783 1,000109 0,410 -1,533 0,41011 0,462 -1,093 0,462116 0,410 -1,533 0,410117 0,370 -1,872 0,370118 0,550 -0,348 0,55012 0,622 0,211 0,622120 0,432 -1,347 0,432121 0,520 -0,602 0,520122 0,450 -1,194 0,450123 0,480 -0,940 0,480124 0,770 1,218 0,770125 0,829 1,619 0,82913 0,592 0,006 0,59214 0,470 -1,025 0,470140 0,500 -0,771 0,500142 0,840 1,694 0,840147 0,513 -0,661 0,513149 0,700 0,741 0,70018 0,440 -1,279 0,44019 0,920 2,238 0,9202 0,590 -0,009 0,59022 0,570 -0,178 0,57024 0,560 -0,263 0,56026 0,540 -0,429 0,54030 0,825 1,592 0,82531 0,662 0,483 0,66232 0,510 -0,686 0,51034 0,590 -0,009 0,59036 0,559 -0,271 0,55938 0,553 -0,322 0,5534 0,540 -0,432 0,54041 0,780 1,286 0,78042 0,790 1,354 0,79044 0,660 0,469 0,66047 0,560 -0,263 0,56048 0,595 0,027 0,595


49 0,530 -0,517 0,5305 0,690 0,673 0,69051 0,620 0,197 0,62052 0,690 0,673 0,69053 1,140 3,735 1,14054 0,650 0,401 0,65056 0,580 -0,094 0,58059 0,668 0,524 0,6686 0,580 -0,094 0,58064 0,430 -1,364 0,43065 0,571 -0,170 0,5717 0,670 0,537 0,6708 0,560 -0,263 0,56080 0,533 -0,491 0,53387 0,800 1,422 0,80088 0,510 -0,686 0,51089 0,500 -0,771 0,5009 0,850 1,762 0,85094 0,740 1,014 0,74099 0,560 -0,263 0,560



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Trichlorethen

DIN 38402 A45

63

0,325 - 0,890 µg/l (|Zu-Score| < 2,00)



23,93% (Limited)

23,93%

0,137 µg/l

ProLab 2009

Labor

106 31 142 64 49 18 120

117 26 14 123 80 7 89 10 88 147 36 140 87 108 22 38 32 107

116

122 19 121 2 65 99 8 59 4 13 42 47 54 56 12 5 52 6 34 118 11 125

149 30 104 48 24 109 44 103 41 9 94 124 51 53 78

µg/l

1,3

1,2

1,1

1

0,9

0,8

0,7

0,6

0,5

0,4

0,3

0,2

0,1

0

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Trichlorethen

DIN 38402 A45

63

0,325 - 0,890 µg/l (|Zu-Score| < 2,00)



23,93% (Limited)

23,93%

0,137 µg/l


10 0,490 -0,674 0,490103 0,780 1,302 0,780104 0,730 0,986 0,730106 0,180 -3,163 0,180107 0,550 -0,193 0,550108 0,507 -0,538 0,507109 0,750 1,113 0,75011 0,666 0,582 0,666116 0,550 -0,193 0,550117 0,440 -1,076 0,440118 0,650 0,481 0,65012 0,607 0,209 0,607120 0,431 -1,148 0,431121 0,560 -0,112 0,560122 0,550 -0,193 0,550123 0,460 -0,915 0,460124 0,890 1,998 0,890125 0,672 0,620 0,67213 0,596 0,139 0,59614 0,450 -0,995 0,450140 0,500 -0,594 0,500142 0,370 -1,638 0,370147 0,496 -0,626 0,496149 0,680 0,670 0,68018 0,410 -1,317 0,41019 0,550 -0,193 0,5502 0,560 -0,112 0,56022 0,510 -0,514 0,51024 0,740 1,049 0,74026 0,443 -1,052 0,44330 0,705 0,828 0,70531 0,361 -1,710 0,36132 0,540 -0,273 0,54034 0,630 0,354 0,63036 0,498 -0,610 0,49838 0,518 -0,449 0,5184 0,590 0,101 0,59041 0,800 1,429 0,80042 0,600 0,164 0,60044 0,760 1,176 0,76047 0,600 0,164 0,60048 0,735 1,018 0,735


49 0,400 -1,397 0,4005 0,610 0,228 0,61051 0,920 2,187 0,92052 0,620 0,291 0,62053 1,250 4,273 1,25054 0,600 0,164 0,60056 0,600 0,164 0,60059 0,589 0,095 0,5896 0,620 0,291 0,62064 0,370 -1,638 0,37065 0,560 -0,112 0,5607 0,470 -0,835 0,47078 5,250 29,558 5,2508 0,570 -0,032 0,57080 0,464 -0,883 0,46487 0,500 -0,594 0,50088 0,490 -0,674 0,49089 0,480 -0,755 0,4809 0,830 1,618 0,83094 0,848 1,732 0,84899 0,560 -0,112 0,560



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Trichlormethan

DIN 38402 A45

63

5,655 - 9,520 µg/l (|Zu-Score| < 2,00)



12,84% (Limited)

12,84%

0,958 µg/l

ProLab 2009

Labor

118 18 14 142 2 9

121 26 122 7

117

106

147 4 99 56 123 89 38 65 44 54 10 32 49 107

149 19 8 24 47 48 31 13 108 34 64 53 80 59 125 36 140 5 52 116 6 42 11 22 88 103 94 124 30 109 12 41 104 87 120 51 78

µg/l

16

15

14

13

12

11

10

9

8

7

6

5

4

3

2

1

0

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


B

Trichlormethan

DIN 38402 A45

63

5,655 - 9,520 µg/l (|Zu-Score| < 2,00)



12,84% (Limited)

12,84%

0,958 µg/l


10 7,090 -0,413 7,090103 8,300 0,813 8,300104 9,850 2,321 9,850106 6,810 -0,723 6,810107 7,140 -0,358 7,140108 7,490 0,025 7,490109 9,300 1,786 9,30011 8,030 0,551 8,030116 8,000 0,521 8,000117 6,790 -0,745 6,790118 3,460 -4,427 3,46012 9,640 2,116 9,640120 10,915 3,356 10,915121 6,370 -1,209 6,370122 6,470 -1,099 6,470123 6,960 -0,557 6,960124 8,890 1,387 8,890125 7,720 0,249 7,72013 7,460 -0,004 7,46014 6,090 -1,519 6,090140 7,750 0,278 7,750142 6,300 -1,287 6,300147 6,810 -0,723 6,810149 7,180 -0,314 7,18018 4,680 -3,078 4,68019 7,240 -0,247 7,2402 6,300 -1,287 6,30022 8,100 0,619 8,10024 7,360 -0,115 7,36026 6,398 -1,178 6,39830 8,910 1,406 8,91031 7,436 -0,031 7,43632 7,100 -0,402 7,10034 7,530 0,064 7,53036 7,740 0,269 7,74038 7,015 -0,496 7,0154 6,850 -0,679 6,85041 9,800 2,272 9,80042 8,010 0,531 8,01044 7,060 -0,446 7,06047 7,400 -0,071 7,40048 7,425 -0,043 7,425


49 7,100 -0,402 7,1005 7,770 0,298 7,77051 10,940 3,381 10,94052 7,820 0,346 7,82053 7,640 0,171 7,64054 7,060 -0,446 7,06056 6,930 -0,590 6,93059 7,660 0,191 7,6606 8,000 0,521 8,00064 7,620 0,152 7,62065 7,052 -0,455 7,0527 6,630 -0,922 6,63078 16,280 8,574 16,2808 7,300 -0,181 7,30080 7,643 0,174 7,64387 10,800 3,244 10,80088 8,260 0,774 8,26089 7,000 -0,513 7,0009 6,320 -1,265 6,32094 8,684 1,187 8,68499 6,900 -0,623 6,900


Vergleichs-STD











Ringversuchskenndaten Charge C



CProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


100

104104104104104104104104105105105105105105105105

108108108108108108108108

1111111111111111110110110110110110110110

111111111111111111111111113113113113113113113113

114114114114114114114114118118118118118118118

120120120120120120120120126126126126126126126126

127127127127127127127127128

129129129129129129129129

1313131313131313130130130130130130130130

131131131131131131131131140140140140140140140140

141141141141141141141141143143143143143143143143

144144144144144144144144148148148148148148148148

15151515151515151616161616161616

1717171717171717

18181818181818181919191919191919

21212121212122222222222222

6,50

2,48

10,88

2,49

2,13

4,88

3,80

3,23

-2,90

-2,14

-2,49

-2,05

-2,60 -2,09 -2,59

-3,81

-2,96

quo data



CProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


39393939393944444444

414141414141454545454545454547474747474747474949494949494949

5555555550505050505050505151515151515151555555555555556666666666666666

67676767676767676868686868686868696969696969696970707070707070707171717171717171

72727272727272727474747474747474777777777777777778787878818181818181818282828282828282

83838383838383839999999

9090909091919191919191919595959595959595

2,35

2,05

2,56

2,62

2,14

2,35

16,27

2,23

3,322,35

2,81

2,83

2,79

2,41

2,36

2,03

2,78

2,11

3,00

8,50-2,76

-2,99

-2,06

-3,11 -3,47

-2,32

-3,70

-3,08 -2,96

quo data



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

1,2-Dichlorethan

DIN 38402 A45

56

6,549 - 13,788 µg/l (|Zu-Score| < 2,00)



18,09% (Limited)

18,09%

1,780 µg/l

ProLab 2009

Labor

148 78 141 25 114

131 16 72 49 120 50 26 66 3 18 68 5

113 19 71 77 104 17 130 22 144

105

127 83 126 23 47 82 11 143 81 15 4

110 55 74 108

129 13 140 70 118 67 69 9 95 45 24 91 51 111

µg/l

23

22

21

20

19

18

17

16

15

14

13

12

11

10

9

8

7

6

5

4

Mittelw

ert

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

1,2-Dichlorethan

DIN 38402 A45

56

6,549 - 13,788 µg/l (|Zu-Score| < 2,00)



18,09% (Limited)

18,09%

1,780 µg/l


104 9,350 -0,299 9,350105 9,740 -0,062 9,740108 10,800 0,485 10,80011 10,300 0,232 10,300110 10,693 0,431 10,693111 22,670 6,502 22,670113 9,144 -0,424 9,144114 7,800 -1,240 7,800118 11,500 0,840 11,500120 8,233 -0,978 8,233126 9,970 0,065 9,970127 9,860 0,009 9,860129 10,810 0,490 10,81013 10,900 0,536 10,900130 9,450 -0,238 9,450131 7,860 -1,204 7,860140 10,950 0,561 10,950141 7,160 -1,629 7,160143 10,310 0,237 10,310144 9,722 -0,073 9,722148 5,060 -2,904 5,06015 10,430 0,298 10,43016 8,098 -1,060 8,09817 9,384 -0,279 9,38418 8,800 -0,633 8,80019 9,200 -0,390 9,20022 9,600 -0,147 9,60023 9,990 0,075 9,99024 13,710 1,960 13,71025 7,260 -1,568 7,26026 8,494 -0,819 8,4943 8,790 -0,639 8,7904 10,450 0,308 10,45045 13,000 1,600 13,00047 10,000 0,080 10,00049 8,230 -0,979 8,2305 9,040 -0,487 9,04050 8,390 -0,882 8,39051 14,480 2,351 14,48055 10,710 0,440 10,71066 8,730 -0,676 8,73067 11,900 1,043 11,900


68 8,820 -0,621 8,82069 12,100 1,144 12,10070 11,200 0,688 11,20071 9,220 -0,378 9,22072 8,210 -0,991 8,21074 10,760 0,465 10,76077 9,260 -0,354 9,26078 5,300 -2,759 5,30081 10,400 0,282 10,40082 10,020 0,090 10,02083 9,890 0,024 9,8909 12,500 1,347 12,50091 13,880 2,047 13,88095 12,810 1,504 12,810



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Benzol

DIN 38402 A45

54

2,754 - 6,323 µg/l (|Zu-Score| < 2,00)



20,05% (Limited)

20,05%

0,874 µg/l

ProLab 2009

Labor

72 18 16 70 141 25 3 45 110 49 114

120 50 68 100

131

105 77 74 71 113 26 143 83 144

111

130 4

140 81 129

128 19 47 108

127 95 15 5 11 23 126 67 104 66 82 148 24 69 1 17 91 13 51

µg/l

7,5

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Benzol

DIN 38402 A45

54

2,754 - 6,323 µg/l (|Zu-Score| < 2,00)



20,05% (Limited)

20,05%

0,874 µg/l


1 5,560 1,222 5,560100 3,700 -0,823 3,700104 5,240 0,896 5,240105 3,840 -0,648 3,840108 4,540 0,183 4,54011 4,750 0,397 4,750110 3,615 -0,929 3,615111 4,314 -0,058 4,314113 4,051 -0,386 4,051114 3,640 -0,897 3,640120 3,650 -0,885 3,650126 5,060 0,713 5,060127 4,610 0,254 4,610128 4,490 0,132 4,490129 4,480 0,122 4,48013 6,790 2,476 6,790130 4,330 -0,038 4,330131 3,740 -0,773 3,740140 4,400 0,040 4,400141 3,400 -1,196 3,400143 4,140 -0,275 4,140144 4,311 -0,062 4,311148 5,480 1,141 5,48015 4,690 0,336 4,69016 3,153 -1,504 3,15317 5,722 1,387 5,72218 3,110 -1,557 3,11019 4,490 0,132 4,49023 4,800 0,448 4,80024 5,480 1,141 5,48025 3,400 -1,196 3,40026 4,079 -0,351 4,0793 3,600 -0,947 3,6004 4,350 -0,013 4,35045 3,600 -0,947 3,60047 4,500 0,142 4,50049 3,630 -0,910 3,6305 4,690 0,336 4,69050 3,670 -0,860 3,67051 6,870 2,557 6,87066 5,320 0,978 5,32067 5,080 0,733 5,080


68 3,690 -0,835 3,69069 5,480 1,141 5,48070 3,160 -1,495 3,16071 3,980 -0,474 3,98072 1,960 -2,989 1,96074 3,940 -0,524 3,94077 3,880 -0,599 3,88081 4,460 0,101 4,46082 5,340 0,998 5,34083 4,170 -0,238 4,17091 5,920 1,589 5,92095 4,660 0,305 4,660



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Bromdichlormethan

DIN 38402 A45

60

2,906 - 4,942 µg/l (|Zu-Score| < 2,00)



13,08% (Limited)

13,08%

0,504 µg/l

ProLab 2009

Labor

3 18 25 148 66 114 72 141

110

105 50 81 16 77 5 49 120 19 68 4 55 127 83 67 26 140 47 144

126

130 24 13 21 143

131 71 74 11 39 113

129 17 118 23 70 45 104 15 1 82 22 108 90 9

111 95 69 51 91 41

µg/l

5,4

5,2

5

4,8

4,6

4,4

4,2

4

3,8

3,6

3,4

3,2

3

2,8

2,6

2,4

2,2

2

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Bromdichlormethan

DIN 38402 A45

60

2,906 - 4,942 µg/l (|Zu-Score| < 2,00)



13,08% (Limited)

13,08%

0,504 µg/l


1 4,300 0,816 4,300104 4,270 0,761 4,270105 3,440 -0,878 3,440108 4,470 1,130 4,47011 3,950 0,170 3,950110 3,234 -1,311 3,234111 4,843 1,818 4,843113 3,992 0,248 3,992114 3,120 -1,551 3,120118 4,080 0,410 4,080120 3,620 -0,500 3,620126 3,820 -0,079 3,820127 3,720 -0,290 3,720129 4,030 0,318 4,03013 3,840 -0,037 3,840130 3,820 -0,079 3,820131 3,890 0,060 3,890140 3,800 -0,121 3,800141 3,230 -1,320 3,230143 3,870 0,023 3,870144 3,802 -0,117 3,802148 3,030 -1,740 3,03015 4,270 0,761 4,27016 3,465 -0,826 3,46517 4,056 0,366 4,05618 2,840 -2,140 2,84019 3,620 -0,500 3,62021 3,840 -0,037 3,84022 4,400 1,001 4,40023 4,120 0,484 4,12024 3,830 -0,058 3,83025 2,880 -2,056 2,88026 3,787 -0,149 3,7873 2,380 -3,107 2,38039 3,950 0,170 3,9504 3,650 -0,437 3,65041 5,280 2,624 5,28045 4,200 0,632 4,20047 3,800 -0,121 3,80049 3,590 -0,563 3,5905 3,580 -0,584 3,58050 3,440 -0,878 3,440


51 5,020 2,144 5,02055 3,660 -0,416 3,66066 3,080 -1,635 3,08067 3,750 -0,226 3,75068 3,630 -0,479 3,63069 4,900 1,923 4,90070 4,160 0,558 4,16071 3,900 0,078 3,90072 3,190 -1,404 3,19074 3,940 0,152 3,94077 3,510 -0,731 3,51081 3,450 -0,857 3,45082 4,310 0,834 4,31083 3,730 -0,268 3,7309 4,630 1,425 4,63090 4,530 1,240 4,53091 5,130 2,347 5,13095 4,880 1,886 4,880



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Dibromchlormethan

DIN 38402 A45

59

0,528 - 0,963 µg/l (|Zu-Score| < 2,00)



14,75% (Limited)

14,75%

0,108 µg/l

ProLab 2009

Labor

3 25 110

120 50 148

140 18 23 126 66 39 72 127 71 114 22 5 4 45 49 67 131 83 104 19 11 47 55 74 90 111 16 13 105

129

144 17 26 70 143 69 130 15 9 24 141

118 77 82 91 95 51 113 68 108 21 1 41

µg/l

1,5

1,4

1,3

1,2

1,1

1

0,9

0,8

0,7

0,6

0,5

0,4

0,3

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Dibromchlormethan

DIN 38402 A45

59

0,528 - 0,963 µg/l (|Zu-Score| < 2,00)



14,75% (Limited)

14,75%

0,108 µg/l


1 2,000 10,875 2,000104 0,720 -0,095 0,720105 0,744 0,123 0,744108 1,020 2,486 1,02011 0,723 -0,066 0,723110 0,573 -1,554 0,573111 0,731 0,012 0,731113 0,978 2,126 0,978114 0,680 -0,492 0,680118 0,850 1,031 0,850120 0,579 -1,494 0,579126 0,640 -0,889 0,640127 0,665 -0,641 0,665129 0,750 0,174 0,75013 0,741 0,097 0,741130 0,780 0,431 0,780131 0,710 -0,195 0,710140 0,600 -1,286 0,600141 0,840 0,945 0,840143 0,770 0,346 0,770144 0,756 0,226 0,756148 0,596 -1,325 0,59615 0,780 0,431 0,78016 0,735 0,046 0,73517 0,758 0,243 0,75818 0,600 -1,286 0,60019 0,720 -0,095 0,72021 1,300 4,883 1,30022 0,690 -0,393 0,69023 0,620 -1,087 0,62024 0,830 0,859 0,83025 0,560 -1,683 0,56026 0,758 0,244 0,7583 0,380 -3,468 0,38039 0,650 -0,790 0,6504 0,700 -0,294 0,70041 2,630 16,269 2,63045 0,700 -0,294 0,70047 0,730 0,003 0,73049 0,700 -0,294 0,7005 0,690 -0,393 0,69050 0,590 -1,385 0,590


51 0,940 1,801 0,94055 0,730 0,003 0,73066 0,640 -0,889 0,64067 0,708 -0,214 0,70868 0,990 2,229 0,99069 0,770 0,346 0,77070 0,760 0,260 0,76071 0,670 -0,591 0,67072 0,660 -0,691 0,66074 0,730 0,003 0,73077 0,865 1,159 0,86582 0,890 1,373 0,89083 0,717 -0,125 0,7179 0,780 0,431 0,78090 0,730 0,003 0,73091 0,910 1,544 0,91095 0,917 1,604 0,917



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Tetrachlorethen

DIN 38402 A45

59

3,709 - 6,812 µg/l (|Zu-Score| < 2,00)



14,91% (Limited)

14,91%

0,767 µg/l

ProLab 2009

Labor

78 18 141 25 16 72 114

120 77 110

127 71 144 49 108

111 39 4

105

148 68 3 81 21 130

113 82 55 19 5

131 74 126 26 95 67 70 83 47 23 50 15 140 17 13 22 143

104 11 9 24 129 91 118 45 69 51 66 41

µg/l

8,5

8

7,5

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

Mittelw

ert

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Tetrachlorethen

DIN 38402 A45

59

3,709 - 6,812 µg/l (|Zu-Score| < 2,00)



14,91% (Limited)

14,91%

0,767 µg/l


104 5,700 0,666 5,700105 4,850 -0,411 4,850108 4,750 -0,551 4,75011 5,780 0,762 5,780110 4,525 -0,864 4,525111 4,786 -0,501 4,786113 5,012 -0,186 5,012114 3,980 -1,623 3,980118 6,340 1,434 6,340120 4,144 -1,395 4,144126 5,210 0,078 5,210127 4,580 -0,787 4,580129 6,180 1,242 6,18013 5,560 0,498 5,560130 5,000 -0,203 5,000131 5,160 0,018 5,160140 5,500 0,426 5,500141 3,360 -2,487 3,360143 5,660 0,618 5,660144 4,664 -0,670 4,664148 4,850 -0,411 4,85015 5,480 0,402 5,48016 3,675 -2,048 3,67517 5,501 0,427 5,50118 3,280 -2,598 3,28019 5,130 -0,021 5,13021 4,990 -0,216 4,99022 5,600 0,546 5,60023 5,440 0,354 5,44024 6,070 1,110 6,07025 3,480 -2,319 3,48026 5,227 0,098 5,2273 4,940 -0,286 4,94039 4,830 -0,439 4,8304 4,830 -0,439 4,83041 7,910 3,318 7,91045 7,100 2,346 7,10047 5,400 0,306 5,40049 4,700 -0,620 4,7005 5,130 -0,021 5,13050 5,440 0,354 5,44051 7,490 2,814 7,490


55 5,060 -0,119 5,06066 7,500 2,826 7,50067 5,260 0,138 5,26068 4,930 -0,300 4,93069 7,470 2,790 7,47070 5,370 0,270 5,37071 4,660 -0,676 4,66072 3,720 -1,985 3,72074 5,180 0,042 5,18077 4,300 -1,177 4,30078 2,490 -3,698 2,49081 4,950 -0,272 4,95082 5,040 -0,147 5,04083 5,370 0,270 5,3709 5,880 0,882 5,88091 6,210 1,278 6,21095 5,240 0,114 5,240



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Tribrommethan

DIN 38402 A45

60

1,849 - 3,273 µg/l (|Zu-Score| < 2,00)



14,04% (Limited)

14,04%

0,352 µg/l

ProLab 2009

Labor

3 18 81 25 11 114

110 39 148 68 72 141 66 104

130

140 49 4 22 26 131

127

126 77 67 105

120 5 55 71 23 47 24 144 13 143 15 83 50 70 16 82 21 129

118

111 90 17 51 19 1 74 95 9

113 69 45 91 41 108

µg/l

4,2

4

3,8

3,6

3,4

3,2

3

2,8

2,6

2,4

2,2

2

1,8

1,6

1,4

1,2

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Tribrommethan

DIN 38402 A45

60

1,849 - 3,273 µg/l (|Zu-Score| < 2,00)



14,04% (Limited)

14,04%

0,352 µg/l


1 2,900 1,022 2,900104 2,220 -0,879 2,220105 2,460 -0,154 2,460108 3,960 3,804 3,96011 2,110 -1,211 2,110110 2,139 -1,123 2,139111 2,736 0,591 2,736113 3,054 1,426 3,054114 2,130 -1,150 2,130118 2,710 0,523 2,710120 2,472 -0,117 2,472126 2,410 -0,305 2,410127 2,400 -0,335 2,400129 2,690 0,470 2,69013 2,530 0,050 2,530130 2,270 -0,728 2,270131 2,360 -0,456 2,360140 2,300 -0,637 2,300141 2,200 -0,939 2,200143 2,530 0,050 2,530144 2,511 0,000 2,511148 2,150 -1,090 2,15015 2,540 0,076 2,54016 2,655 0,378 2,65517 2,785 0,720 2,78518 1,820 -2,087 1,82019 2,880 0,969 2,88021 2,680 0,444 2,68022 2,350 -0,486 2,35023 2,490 -0,063 2,49024 2,510 -0,003 2,51025 2,100 -1,241 2,10026 2,356 -0,468 2,3563 1,490 -3,084 1,49039 2,140 -1,120 2,1404 2,320 -0,577 2,32041 3,430 2,413 3,43045 3,200 1,809 3,20047 2,500 -0,033 2,50049 2,300 -0,637 2,3005 2,480 -0,093 2,48050 2,580 0,181 2,580


51 2,870 0,943 2,87055 2,480 -0,093 2,48066 2,210 -0,909 2,21067 2,440 -0,214 2,44068 2,160 -1,060 2,16069 3,140 1,652 3,14070 2,580 0,181 2,58071 2,480 -0,093 2,48072 2,190 -0,969 2,19074 2,990 1,258 2,99077 2,410 -0,305 2,41081 2,080 -1,302 2,08082 2,660 0,391 2,66083 2,560 0,129 2,5609 3,050 1,415 3,05090 2,760 0,654 2,76091 3,410 2,360 3,41095 3,040 1,389 3,040



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Trichlorethen

DIN 38402 A45

59

1,973 - 4,073 µg/l (|Zu-Score| < 2,00)



17,64% (Limited)

17,64%

0,517 µg/l

ProLab 2009

Labor

18 72 16 68 114 25 141

120

148

130 81 110 26 82 3 55 108 19 113 71 127 77 49 4 74 95 50 105 15 5 39 67 144 23 140

131

126

143 17 13 83 104 70 47 111 24 11 45 66 21 118

129 22 78 69 9 91 41 51

µg/l

4,6

4,4

4,2

4

3,8

3,6

3,4

3,2

3

2,8

2,6

2,4

2,2

2

1,8

1,6

1,4

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Trichlorethen

DIN 38402 A45

59

1,973 - 4,073 µg/l (|Zu-Score| < 2,00)



17,64% (Limited)

17,64%

0,517 µg/l


104 3,170 0,419 3,170105 2,920 -0,022 2,920108 2,620 -0,649 2,62011 3,380 0,787 3,380110 2,537 -0,822 2,537111 3,203 0,477 3,203113 2,655 -0,575 2,655114 2,250 -1,421 2,250118 3,490 0,980 3,490120 2,463 -0,976 2,463126 3,080 0,262 3,080127 2,700 -0,481 2,700129 3,490 0,980 3,49013 3,160 0,402 3,160130 2,520 -0,857 2,520131 3,060 0,227 3,060140 3,000 0,122 3,000141 2,280 -1,359 2,280143 3,120 0,332 3,120144 2,972 0,073 2,972148 2,470 -0,962 2,47015 2,930 -0,001 2,93016 2,183 -1,561 2,18317 3,155 0,393 3,15518 1,690 -2,591 1,69019 2,630 -0,628 2,63021 3,470 0,945 3,47022 3,500 0,997 3,50023 2,980 0,087 2,98024 3,260 0,577 3,26025 2,250 -1,421 2,25026 2,559 -0,776 2,5593 2,580 -0,732 2,58039 2,970 0,069 2,9704 2,750 -0,377 2,75041 4,090 2,031 4,09045 3,400 0,822 3,40047 3,200 0,472 3,20049 2,740 -0,398 2,7405 2,960 0,052 2,96050 2,890 -0,085 2,89051 4,520 2,784 4,520


55 2,580 -0,732 2,58066 3,410 0,840 3,41067 2,970 0,069 2,97068 2,230 -1,463 2,23069 3,630 1,225 3,63070 3,180 0,437 3,18071 2,670 -0,544 2,67072 2,020 -1,902 2,02074 2,810 -0,252 2,81077 2,730 -0,419 2,73078 3,530 1,050 3,53081 2,530 -0,836 2,53082 2,560 -0,774 2,56083 3,160 0,402 3,1609 3,750 1,435 3,75091 3,800 1,523 3,80095 2,870 -0,126 2,870



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Trichlormethan

DIN 38402 A45

61

3,976 - 7,151 µg/l (|Zu-Score| < 2,00)



14,42% (Limited)

14,42%

0,786 µg/l

ProLab 2009

Labor

118 18 3

141 72 25 16 9

110

148

127 68 71 77 4

114 74 82 49 26 39 50 83 105 47 108 5 19 24 113

143 55 13 23 66 144

140 81 17 131 11 126

130 67 1 15 129 90 70 95 104 21 22 45 111 69 91 41 51 120 78

µg/l

1312,5

1211,5

11

10,510

9,5

98,5

8

7,57

6,56

5,55

4,5

43,5

3

2,52

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


C

Trichlormethan

DIN 38402 A45

61

3,976 - 7,151 µg/l (|Zu-Score| < 2,00)



14,42% (Limited)

14,42%

0,786 µg/l


1 5,800 0,413 5,800104 6,240 0,930 6,240105 5,330 -0,162 5,330108 5,420 -0,039 5,42011 5,650 0,236 5,650110 4,738 -0,965 4,738111 6,461 1,189 6,461113 5,470 0,025 5,470114 5,030 -0,569 5,030118 2,640 -3,813 2,640120 8,197 3,230 8,197126 5,660 0,248 5,660127 4,750 -0,949 4,750129 5,980 0,624 5,98013 5,520 0,083 5,520130 5,660 0,248 5,660131 5,640 0,224 5,640140 5,600 0,177 5,600141 4,190 -1,709 4,190143 5,470 0,025 5,470144 5,584 0,159 5,584148 4,740 -0,962 4,74015 5,950 0,589 5,95016 4,508 -1,277 4,50817 5,605 0,183 5,60518 3,270 -2,958 3,27019 5,450 0,001 5,45021 6,290 0,988 6,29022 6,300 1,000 6,30023 5,520 0,083 5,52024 5,450 0,001 5,45025 4,380 -1,451 4,38026 5,157 -0,396 5,1573 3,270 -2,958 3,27039 5,170 -0,379 5,1704 4,990 -0,623 4,99041 7,240 2,105 7,24045 6,400 1,118 6,40047 5,400 -0,067 5,40049 5,100 -0,474 5,1005 5,430 -0,026 5,43050 5,230 -0,297 5,230


51 8,000 2,998 8,00055 5,470 0,025 5,47066 5,520 0,083 5,52067 5,710 0,307 5,71068 4,880 -0,772 4,88069 7,060 1,893 7,06070 6,120 0,789 6,12071 4,940 -0,691 4,94072 4,230 -1,655 4,23074 5,080 -0,501 5,08077 4,950 -0,677 4,95078 12,680 8,499 12,68081 5,600 0,177 5,60082 5,090 -0,487 5,09083 5,270 -0,243 5,2709 4,600 -1,152 4,60090 6,060 0,718 6,06091 7,100 1,940 7,10095 6,220 0,906 6,220


Vergleichs-STD











Ringversuchskenndaten Charge D



DProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


101101101101101101101101

105105105105105105105105

106106106106106106106106

112112112112112112112112

114114114114114114114114

115

1161161161161161161161161212121212121212

120120120120120120120120

126126126126126126126126

127127127127127127127127

128

129129129129129129129129

131131131131131131131131

132132132132132132

138138138138138138138138

1414141414141414

144144144144144144144144

145145145145145145145145

146146146146146146146146

148148148148148148148148149149149149149149149149

150150150150150150150150

2222222

2727272727272727

2828282828282828

29

3030303030303030

3131313131313131

13,57 3,62

2,09

5,86

2,73

4,80

2,35

-2,01

-3,40 -3,43-2,07-5,24

-3,50

-5,65

-3,53-2,17

-2,03

-2,30

-3,68 -6,57

-4,33

-6,01

-2,68

-5,43

quo data



DProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


343434343434343435353535353535

3636363636363636

37373737373737373838383838383838

40404040404040404242424242424242

4343434343434444444444444444

484848484848485252525252525252

5555555555555566666666

6767676767676767

68686868686868686969696969696969

777777777070707070707070

71717171717171717272727272727272

73737373737373737474747474747474

76767676767676767777777777777777

7979797979797979

888888888383838383838383

92929292929292929696969696969696

2,37

2,79

2,71

2,95

3,29

4,45

3,57

2,21 4,67

2,93

3,09

-2,58

-2,62 -2,19

quo data



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

1,2-Dichlorethan

DIN 38402 A45

56

0,915 - 2,443 µg/l (|Zu-Score| < 2,00)



23,39% (Limited)

23,39%

0,372 µg/l

ProLab 2009

Labor

146 44 131

145 14 148

106

114 55 32 10 74 72 150

120

112 36 38 138 83 71 2 8

116 73 127 77 31 68 96 12 144 34 37 79 126 33 52 40 42 30 67 35 7

149 76 27 6

101 69 48 105 92 129 70 28

µg/l

32,82,62,42,2

21,81,6

1,41,2

10,80,60,40,2

0

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

1,2-Dichlorethan

DIN 38402 A45

56

0,915 - 2,443 µg/l (|Zu-Score| < 2,00)



23,39% (Limited)

23,39%

0,372 µg/l


10 1,330 -0,770 1,330101 2,070 1,125 2,070105 2,230 1,500 2,230106 1,200 -1,155 1,200112 1,380 -0,622 1,380114 1,220 -1,096 1,220116 1,520 -0,208 1,52012 1,610 0,047 1,610120 1,360 -0,681 1,360126 1,670 0,187 1,670127 1,550 -0,119 1,550129 2,380 1,851 2,380131 0,910 -2,014 0,910138 1,460 -0,385 1,46014 1,160 -1,273 1,160144 1,612 0,051 1,612145 1,100 -1,451 1,100146 0,443 -3,396 0,443148 1,190 -1,185 1,190149 1,920 0,773 1,920150 1,358 -0,687 1,3582 1,500 -0,267 1,50027 1,990 0,937 1,99028 7,379 13,568 7,37930 1,800 0,492 1,80031 1,575 -0,045 1,57532 1,300 -0,859 1,30033 1,670 0,187 1,67034 1,620 0,070 1,62035 1,839 0,583 1,83936 1,380 -0,622 1,38037 1,623 0,077 1,62338 1,450 -0,415 1,45040 1,720 0,304 1,72042 1,760 0,398 1,76044 0,720 -2,576 0,72048 2,110 1,218 2,11052 1,690 0,234 1,69055 1,240 -1,037 1,2406 2,020 1,008 2,02067 1,820 0,539 1,82068 1,580 -0,030 1,580


69 2,100 1,195 2,1007 1,840 0,586 1,84070 2,600 2,367 2,60071 1,480 -0,326 1,48072 1,340 -0,741 1,34073 1,520 -0,208 1,52074 1,330 -0,770 1,33076 1,950 0,843 1,95077 1,570 -0,060 1,57079 1,660 0,164 1,6608 1,500 -0,267 1,50083 1,470 -0,356 1,47092 2,300 1,664 2,30096 1,580 -0,030 1,580



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Benzol

DIN 38402 A45

55

1,848 - 4,287 µg/l (|Zu-Score| < 2,00)



20,29% (Limited)

20,29%

0,597 µg/l

ProLab 2009

Labor

146 72 112

106 44 115

114 14 70 120

105

131 74 77 8 79 150 71 36 128 27 38 68 31 32 83 116 33 144 29 52 126 76 34 101

138 7

129 12 37 10 40 73 148 67 127 30 6 69 145 42 92 149 96 28

µg/l

5,5

5

4,5

4

3,5

3

2,5

2

1,5

1

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Benzol

DIN 38402 A45

55

1,848 - 4,287 µg/l (|Zu-Score| < 2,00)



20,29% (Limited)

20,29%

0,597 µg/l


10 3,280 0,500 3,280101 3,110 0,247 3,110105 2,480 -0,847 2,480106 1,970 -1,777 1,970112 1,968 -1,780 1,968114 2,290 -1,193 2,290115 2,220 -1,321 2,220116 3,010 0,098 3,01012 3,190 0,366 3,190120 2,475 -0,856 2,475126 3,060 0,173 3,060127 3,530 0,873 3,530128 2,790 -0,281 2,790129 3,180 0,351 3,180131 2,520 -0,774 2,520138 3,110 0,247 3,11014 2,320 -1,138 2,320144 3,030 0,128 3,030145 3,800 1,275 3,800146 1,065 -3,427 1,065148 3,360 0,619 3,360149 4,110 1,736 4,110150 2,669 -0,502 2,66927 2,810 -0,245 2,81028 5,375 3,621 5,37529 3,050 0,158 3,05030 3,540 0,887 3,54031 2,863 -0,148 2,86332 2,900 -0,081 2,90033 3,010 0,098 3,01034 3,090 0,217 3,09036 2,720 -0,409 2,72037 3,211 0,397 3,21138 2,850 -0,172 2,85040 3,300 0,530 3,30042 3,820 1,304 3,82044 2,050 -1,631 2,05052 3,050 0,158 3,0506 3,560 0,917 3,56067 3,520 0,858 3,52068 2,860 -0,154 2,86069 3,570 0,932 3,570


7 3,140 0,292 3,14070 2,320 -1,138 2,32071 2,700 -0,445 2,70072 1,510 -2,616 1,51073 3,310 0,545 3,31074 2,520 -0,774 2,52076 3,060 0,173 3,06077 2,560 -0,701 2,56079 2,610 -0,610 2,6108 2,600 -0,628 2,60083 2,910 -0,062 2,91092 3,900 1,424 3,90096 4,180 1,841 4,180



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Bromdichlormethan

DIN 38402 A45

58

1,366 - 2,385 µg/l (|Zu-Score| < 2,00)



13,71% (Limited)

13,71%

0,252 µg/l

ProLab 2009

Labor

146 27 145 14 114

148 74 150 2 43 72 106 96 120 55 105 36 7 77 38 68 48 79 37 126 44 116 83 67 35 34 144

131 31 32 33 71 112

149 10 52 73 8

127 30 6 12 101 70 129 42 132 76 40 138 28 69 92

µg/l

2,6

2,4

2,2

2

1,8

1,6

1,4

1,2

1

0,8

0,6

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Bromdichlormethan

DIN 38402 A45

58

1,366 - 2,385 µg/l (|Zu-Score| < 2,00)



13,71% (Limited)

13,71%

0,252 µg/l


10 1,960 0,438 1,960101 2,070 0,842 2,070105 1,650 -0,804 1,650106 1,610 -0,973 1,610112 1,941 0,368 1,941114 1,530 -1,310 1,530116 1,810 -0,130 1,81012 2,030 0,695 2,030120 1,640 -0,846 1,640126 1,780 -0,256 1,780127 2,020 0,658 2,020129 2,080 0,879 2,080131 1,870 0,107 1,870132 2,100 0,952 2,100138 2,130 1,062 2,13014 1,390 -1,900 1,390144 1,868 0,100 1,868145 1,350 -2,068 1,350146 0,598 -5,237 0,598148 1,540 -1,268 1,540149 1,950 0,401 1,950150 1,591 -1,053 1,5912 1,600 -1,015 1,60027 1,010 -3,501 1,01028 2,140 1,099 2,14030 2,020 0,658 2,02031 1,893 0,192 1,89332 1,900 0,217 1,90033 1,900 0,217 1,90034 1,850 0,034 1,85035 1,835 -0,025 1,83536 1,700 -0,594 1,70037 1,779 -0,261 1,77938 1,745 -0,404 1,74540 2,120 1,026 2,12042 2,080 0,879 2,08043 1,600 -1,015 1,60044 1,800 -0,172 1,80048 1,770 -0,299 1,77052 1,970 0,474 1,97055 1,640 -0,846 1,6406 2,020 0,658 2,020


67 1,830 -0,046 1,83068 1,760 -0,341 1,76069 2,340 1,834 2,3407 1,720 -0,509 1,72070 2,070 0,842 2,07071 1,910 0,254 1,91072 1,600 -1,015 1,60073 2,000 0,585 2,00074 1,580 -1,099 1,58076 2,100 0,952 2,10077 1,730 -0,467 1,73079 1,770 -0,299 1,7708 2,000 0,585 2,00083 1,820 -0,088 1,82092 2,600 2,789 2,60096 1,610 -0,973 1,610



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Dibromchlormethan

DIN 38402 A45

58

1,112 - 1,901 µg/l (|Zu-Score| < 2,00)



13,22% (Limited)

13,22%

0,196 µg/l

ProLab 2009

Labor

146 27 28 14 72 120

148

106 2 43 74 150

116

126 48 105 37 144 32 38 33 67 34 127 96 55 131 36 10 83 35 112

114

145 77 129 71 101 44 31 70 52 79 8 12 6 40 149 7 76 30 69 42 132 68 138 73 92

µg/l

2,2

2

1,8

1,6

1,4

1,2

1

0,8

0,6

Mittelw

ert

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Dibromchlormethan

DIN 38402 A45

58

1,112 - 1,901 µg/l (|Zu-Score| < 2,00)



13,22% (Limited)

13,22%

0,196 µg/l


10 1,480 -0,002 1,480101 1,530 0,236 1,530105 1,350 -0,707 1,350106 1,250 -1,249 1,250112 1,490 0,046 1,490114 1,490 0,046 1,490116 1,330 -0,815 1,33012 1,620 0,664 1,620120 1,208 -1,477 1,208126 1,330 -0,815 1,330127 1,450 -0,164 1,450129 1,520 0,189 1,520131 1,470 -0,056 1,470132 1,700 1,044 1,700138 1,890 1,947 1,89014 1,140 -1,846 1,140144 1,399 -0,441 1,399145 1,500 0,094 1,500146 0,438 -5,653 0,438148 1,220 -1,412 1,220149 1,650 0,806 1,650150 1,315 -0,897 1,3152 1,300 -0,978 1,30027 0,830 -3,527 0,83028 1,080 -2,171 1,08030 1,670 0,902 1,67031 1,547 0,317 1,54732 1,400 -0,436 1,40033 1,430 -0,273 1,43034 1,440 -0,219 1,44035 1,488 0,036 1,48836 1,470 -0,056 1,47037 1,380 -0,544 1,38038 1,410 -0,381 1,41040 1,640 0,759 1,64042 1,680 0,949 1,68043 1,300 -0,978 1,30044 1,540 0,284 1,54048 1,345 -0,734 1,34552 1,600 0,569 1,60055 1,460 -0,110 1,4606 1,620 0,664 1,620


67 1,430 -0,273 1,43068 1,840 1,710 1,84069 1,670 0,902 1,6707 1,660 0,854 1,66070 1,590 0,521 1,59071 1,520 0,189 1,52072 1,200 -1,520 1,20073 2,050 2,708 2,05074 1,300 -0,978 1,30076 1,660 0,854 1,66077 1,510 0,141 1,51079 1,600 0,569 1,6008 1,600 0,569 1,60083 1,480 -0,002 1,48092 2,100 2,945 2,10096 1,450 -0,164 1,450



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Tetrachlorethen

DIN 38402 A45

58

2,455 - 4,413 µg/l (|Zu-Score| < 2,00)



14,41% (Limited)

14,41%

0,485 µg/l

ProLab 2009

Labor

146 14 106 72 77 114

120 33 73 150

145

127

101

112

132 8 2

105 71 38 31 148 7 74 79 43 37 131 55 27 149 48 6

116 52 36 126

138

144 70 83 67 76 35 32 96 34 10 30 68 12 40 28 42 44 129 69 92

µg/l

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

1

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Tetrachlorethen

DIN 38402 A45

58

2,455 - 4,413 µg/l (|Zu-Score| < 2,00)



14,41% (Limited)

14,41%

0,485 µg/l


10 3,820 0,869 3,820101 3,060 -0,669 3,060105 3,130 -0,515 3,130106 2,440 -2,033 2,440112 3,084 -0,616 3,084114 2,610 -1,659 2,610116 3,470 0,202 3,47012 3,920 1,060 3,920120 2,813 -1,212 2,813126 3,530 0,317 3,530127 3,030 -0,735 3,030129 4,460 2,089 4,460131 3,340 -0,052 3,340132 3,100 -0,581 3,100138 3,530 0,317 3,53014 2,320 -2,297 2,320144 3,551 0,357 3,551145 3,000 -0,801 3,000146 1,693 -3,677 1,693148 3,220 -0,317 3,220149 3,380 0,031 3,380150 2,999 -0,803 2,9992 3,120 -0,537 3,12027 3,360 -0,008 3,36028 4,055 1,317 4,05530 3,870 0,964 3,87031 3,197 -0,367 3,19732 3,700 0,641 3,70033 2,930 -0,955 2,93034 3,790 0,812 3,79035 3,674 0,591 3,67436 3,520 0,298 3,52037 3,334 -0,066 3,33438 3,184 -0,396 3,18440 3,970 1,155 3,97042 4,060 1,327 4,06043 3,300 -0,141 3,30044 4,170 1,536 4,17048 3,440 0,145 3,44052 3,490 0,240 3,49055 3,340 -0,052 3,3406 3,460 0,183 3,460


67 3,590 0,431 3,59068 3,880 0,984 3,88069 5,090 3,289 5,0907 3,240 -0,273 3,24070 3,570 0,393 3,57071 3,150 -0,471 3,15072 2,540 -1,813 2,54073 2,980 -0,845 2,98074 3,240 -0,273 3,24076 3,620 0,488 3,62077 2,600 -1,681 2,60079 3,270 -0,207 3,2708 3,100 -0,581 3,10083 3,580 0,412 3,58092 5,700 4,452 5,70096 3,710 0,660 3,710



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Tribrommethan

DIN 38402 A45

58

6,259 - 9,331 µg/l (|Zu-Score| < 2,00)



9,90% (Limited)

9,90%

0,764 µg/l

ProLab 2009

Labor

146 36 68 2 14 148 43 72 112 27 33 126 7 8 35 105 38 114

144

131

116

132 67 77 96 32 34 55 44 48 120

149 37 71 127

101 52 40 10 12 79 83 42 70 31 28 150 73 129 6 76 30 74 145 92 138 69 106

µg/l

13

12

11

10

9

8

7

6

5

4

3

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Tribrommethan

DIN 38402 A45

58

6,259 - 9,331 µg/l (|Zu-Score| < 2,00)



9,90% (Limited)

9,90%

0,764 µg/l


10 8,030 0,386 8,030101 7,940 0,274 7,940105 7,320 -0,547 7,320106 12,440 5,858 12,440112 7,013 -0,968 7,013114 7,350 -0,506 7,350116 7,400 -0,437 7,40012 8,130 0,510 8,130120 7,629 -0,124 7,629126 7,240 -0,657 7,240127 7,790 0,088 7,790129 8,590 1,080 8,590131 7,380 -0,465 7,380132 7,400 -0,437 7,400138 9,920 2,731 9,92014 6,600 -1,533 6,600144 7,373 -0,474 7,373145 8,850 1,403 8,850146 2,925 -6,568 2,925148 6,620 -1,506 6,620149 7,630 -0,122 7,630150 8,417 0,866 8,4172 6,500 -1,670 6,50027 7,080 -0,876 7,08028 8,405 0,851 8,40530 8,660 1,167 8,66031 8,380 0,820 8,38032 7,500 -0,300 7,50033 7,150 -0,780 7,15034 7,570 -0,204 7,57035 7,306 -0,566 7,30636 6,350 -1,876 6,35037 7,719 0,000 7,71938 7,335 -0,526 7,33540 8,000 0,348 8,00042 8,310 0,733 8,31043 6,700 -1,396 6,70044 7,610 -0,150 7,61048 7,625 -0,129 7,62552 7,970 0,311 7,97055 7,580 -0,191 7,5806 8,600 1,093 8,600


67 7,420 -0,410 7,42068 6,470 -1,711 6,47069 10,600 3,575 10,6007 7,280 -0,602 7,28070 8,340 0,770 8,34071 7,780 0,075 7,78072 6,830 -1,218 6,83073 8,570 1,056 8,57074 8,770 1,304 8,77076 8,650 1,155 8,65077 7,480 -0,328 7,48079 8,160 0,547 8,1608 7,300 -0,574 7,30083 8,280 0,696 8,28092 9,500 2,210 9,50096 7,490 -0,314 7,490



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Trichlorethen

DIN 38402 A45

58

1,595 - 2,823 µg/l (|Zu-Score| < 2,00)



14,03% (Limited)

14,03%

0,304 µg/l

ProLab 2009

Labor

146

106 31 72 114 14 112 2

120

148 43 76 33 68 36 74 101 77 145 27 10 55 71 38 150

105 52 35 116

132 32 127 37 67 6

131 79 8 70 96 28 40 83 149

126 34 73 138 7 12 42 30 144 48 44 129 69 92

µg/l

3,5

3

2,5

2

1,5

1

0,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Trichlorethen

DIN 38402 A45

58

1,595 - 2,823 µg/l (|Zu-Score| < 2,00)



14,03% (Limited)

14,03%

0,304 µg/l


10 2,030 -0,477 2,030101 1,980 -0,652 1,980105 2,150 -0,056 2,150106 0,930 -4,331 0,930112 1,852 -1,100 1,852114 1,620 -1,913 1,620116 2,170 0,012 2,17012 2,420 0,774 2,420120 1,861 -1,069 1,861126 2,380 0,652 2,380127 2,230 0,195 2,230129 2,700 1,627 2,700131 2,280 0,347 2,280132 2,200 0,103 2,200138 2,410 0,743 2,41014 1,700 -1,633 1,700144 2,500 1,017 2,500145 2,000 -0,582 2,000146 0,450 -6,013 0,450148 1,890 -0,967 1,890149 2,370 0,621 2,370150 2,133 -0,116 2,1332 1,860 -1,072 1,86027 2,010 -0,547 2,01028 2,345 0,545 2,34530 2,490 0,987 2,49031 1,401 -2,681 1,40132 2,200 0,103 2,20033 1,940 -0,792 1,94034 2,380 0,652 2,38035 2,159 -0,025 2,15936 1,950 -0,757 1,95037 2,231 0,198 2,23138 2,062 -0,365 2,06240 2,360 0,591 2,36042 2,430 0,804 2,43043 1,900 -0,932 1,90044 2,560 1,200 2,56048 2,515 1,063 2,51552 2,150 -0,056 2,15055 2,030 -0,477 2,0306 2,270 0,317 2,270


67 2,240 0,225 2,24068 1,940 -0,792 1,94069 2,780 1,870 2,7807 2,410 0,743 2,41070 2,320 0,469 2,32071 2,030 -0,477 2,03072 1,540 -2,194 1,54073 2,380 0,652 2,38074 1,960 -0,722 1,96076 1,930 -0,827 1,93077 1,980 -0,652 1,98079 2,290 0,378 2,2908 2,300 0,408 2,30083 2,360 0,591 2,36092 3,700 4,673 3,70096 2,340 0,530 2,340



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Trichlormethan

DIN 38402 A45

58

3,499 - 5,442 µg/l (|Zu-Score| < 2,00)



10,93% (Limited)

10,93%

0,483 µg/l

ProLab 2009

Labor

146 72 112 14 2 31 43 74 148

132 77 79 71 105

106 68 10 145 35 27 38 127 73 114 83 37 36 101 32 7 44 34 144

138

149 52 150 8 67 33 55 48 131 30 126

116 76 96 6

129 42 70 40 12 28 69 92 120

µg/l

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


D

Trichlormethan

DIN 38402 A45

58

3,499 - 5,442 µg/l (|Zu-Score| < 2,00)



10,93% (Limited)

10,93%

0,483 µg/l


10 4,150 -0,583 4,150101 4,360 -0,125 4,360105 4,120 -0,648 4,120106 4,120 -0,648 4,120112 3,603 -1,774 3,603114 4,310 -0,234 4,310116 4,780 0,708 4,78012 5,250 1,625 5,250120 6,878 4,804 6,878126 4,740 0,630 4,740127 4,260 -0,343 4,260129 4,910 0,962 4,910131 4,700 0,552 4,700132 4,000 -0,909 4,000138 4,530 0,220 4,53014 3,660 -1,650 3,660144 4,500 0,161 4,500145 4,150 -0,583 4,150146 1,925 -5,428 1,925148 3,980 -0,953 3,980149 4,530 0,220 4,530150 4,562 0,282 4,5622 3,800 -1,345 3,80027 4,170 -0,539 4,17028 5,620 2,348 5,62030 4,720 0,591 4,72031 3,871 -1,190 3,87132 4,400 -0,038 4,40033 4,620 0,395 4,62034 4,490 0,142 4,49035 4,151 -0,580 4,15136 4,350 -0,147 4,35037 4,325 -0,201 4,32538 4,218 -0,434 4,21840 5,100 1,333 5,10042 4,940 1,020 4,94043 3,900 -1,127 3,90044 4,440 0,044 4,44048 4,675 0,503 4,67552 4,540 0,239 4,54055 4,620 0,395 4,6206 4,870 0,884 4,870


67 4,610 0,376 4,61068 4,140 -0,604 4,14069 5,920 2,934 5,9207 4,430 0,024 4,43070 4,940 1,020 4,94071 4,090 -0,713 4,09072 3,520 -1,955 3,52073 4,300 -0,256 4,30074 3,930 -1,062 3,93076 4,790 0,727 4,79077 4,030 -0,844 4,03079 4,050 -0,800 4,0508 4,600 0,356 4,60083 4,310 -0,234 4,31092 6,000 3,090 6,00096 4,800 0,747 4,800


Vergleichs-STD











Ringversuchskenndaten Charge E



EProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


102102102102102102102102

109109109109109109109109110110110110110110110110

112112112112112112112112

113113113113113113113113115

121121121121121121121121122122122122122122122122

123123123123123123123123130130130130130130130130

132132132132132132133133133133133133133133

134134134134134134134134135135135135135135135135

136136136136136136136136

139139139139139139139139143143143143143143143143

144144144144144144144144145145145145145145145145

146146146146146146146146148148148148148148148148

15151515151515151818181818181818

2222222212121212121

22222222222222

27272727272727273030303030303030

33333333333333333434343434343434

3,01

2,29

2,322,67 7,94

3,00

-4,06-3,62

-2,43

-2,04

-3,84

-2,33 -3,34

-3,45

-4,00

-3,15

-2,41

-2,79

-2,19

-2,16

-4,74

-3,08

-3,56

-2,37

-3,52

-2,95

quo data



EProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


4141414141414242424242424242

434343434343

44444444444444445050505050505050

51515151515151515353535353535353

56565656565656565757575757575757

585858585858585866666666

60606060606060606262626262626262

6464646464646464

69696969696969697272727272727272

73737373737373738080808080808080

818181818181818484848484848484

85858585858585858888888888888888

999999990909090

9393939393939393

94949494949494949595959595959595

96969696969696969797979797979797

3,79 2,32

2,96

2,60

2,108,17

5,37 2,43

2,19

3,44

2,51

2,06

3,18

3,00

2,21

-2,64

-2,09

quo data



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

1,2-Dichlorethan

DIN 38402 A45

55

3,957 - 6,829 µg/l (|Zu-Score| < 2,00)



13,43% (Limited)

13,43%

0,712 µg/l

ProLab 2009

Labor

146

148 18 72 50 123

121 56 44 139

112 62 88 73 93 144 34 113

133

130

122

145 6 96 22 2 58 136 15 10 110 53 97 134

143 33 81 94 60 40 64 42 69 85 30 80 57 84 27 135

102 9 95 109 51

µg/l

8

7,5

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

1,2-Dichlorethan

DIN 38402 A45

55

3,957 - 6,829 µg/l (|Zu-Score| < 2,00)



13,43% (Limited)

13,43%

0,712 µg/l


10 5,320 0,030 5,320102 6,250 1,244 6,250109 7,600 3,006 7,600110 5,329 0,042 5,329112 4,799 -0,744 4,799113 4,986 -0,464 4,986121 4,450 -1,265 4,450122 5,040 -0,384 5,040123 4,390 -1,354 4,390130 5,010 -0,429 5,010133 5,000 -0,444 5,000134 5,410 0,147 5,410135 6,231 1,219 6,231136 5,260 -0,055 5,260139 4,709 -0,878 4,709143 5,440 0,186 5,440144 4,926 -0,554 4,926145 5,050 -0,369 5,050146 2,575 -4,063 2,575148 2,870 -3,623 2,87015 5,310 0,017 5,31018 3,670 -2,429 3,6702 5,200 -0,145 5,20022 5,160 -0,205 5,16027 6,170 1,139 6,17030 6,070 1,009 6,07033 5,460 0,213 5,46034 4,960 -0,503 4,96040 5,620 0,421 5,62042 5,810 0,669 5,81044 4,680 -0,921 4,68050 4,300 -1,488 4,30051 8,200 3,789 8,20053 5,340 0,056 5,34056 4,540 -1,130 4,54057 6,110 1,061 6,11058 5,204 -0,139 5,2046 5,150 -0,220 5,15060 5,530 0,304 5,53062 4,850 -0,667 4,85064 5,700 0,526 5,70069 5,860 0,735 5,860


72 4,170 -1,682 4,17073 4,900 -0,593 4,90080 6,082 1,024 6,08281 5,500 0,265 5,50084 6,168 1,137 6,16885 5,960 0,865 5,96088 4,890 -0,608 4,8909 6,300 1,309 6,30093 4,900 -0,593 4,90094 5,524 0,296 5,52495 6,750 1,896 6,75096 5,150 -0,220 5,15097 5,390 0,121 5,390



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Benzol

DIN 38402 A45

53

1,298 - 3,410 µg/l (|Zu-Score| < 2,00)



23,02% (Limited)

23,02%

0,514 µg/l

ProLab 2009

Labor

133 72 146

112

115 18 121 57 123

110

136 50 139

144

122 93 58 143

130

113

134

109 97 62 81 15 33 53 56 6

135 34 40 60 64 27 95 73 88 145

102 10 148 30 69 44 42 85 96 94 84 51 80

µg/l

4

3,5

3

2,5

2

1,5

1

0,5

Mitte

lwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Benzol

DIN 38402 A45

53

1,298 - 3,410 µg/l (|Zu-Score| < 2,00)



23,02% (Limited)

23,02%

0,514 µg/l


10 2,610 0,640 2,610102 2,560 0,555 2,560109 2,100 -0,285 2,100110 1,834 -0,854 1,834112 1,280 -2,039 1,280113 2,054 -0,383 2,054115 1,530 -1,504 1,530121 1,710 -1,119 1,710122 1,950 -0,606 1,950123 1,820 -0,884 1,820130 2,050 -0,392 2,050133 0,440 -3,836 0,440134 2,060 -0,371 2,060135 2,285 0,088 2,285136 1,880 -0,756 1,880139 1,946 -0,614 1,946143 2,040 -0,413 2,040144 1,946 -0,614 1,946145 2,550 0,538 2,550146 1,145 -2,328 1,145148 2,640 0,691 2,64015 2,180 -0,114 2,18018 1,580 -1,397 1,58027 2,460 0,385 2,46030 2,640 0,691 2,64033 2,180 -0,114 2,18034 2,300 0,113 2,30040 2,310 0,130 2,31042 2,810 0,980 2,81044 2,710 0,810 2,71050 1,890 -0,734 1,89051 3,600 2,323 3,60053 2,240 0,011 2,24056 2,240 0,011 2,24057 1,770 -0,991 1,77058 2,034 -0,426 2,0346 2,260 0,045 2,26060 2,350 0,198 2,35062 2,150 -0,178 2,15064 2,380 0,249 2,38069 2,700 0,793 2,70072 1,000 -2,638 1,000


73 2,500 0,453 2,50080 3,977 2,963 3,97781 2,160 -0,157 2,16084 3,313 1,835 3,31385 3,010 1,320 3,01088 2,500 0,453 2,50093 1,960 -0,585 1,96094 3,060 1,405 3,06095 2,460 0,385 2,46096 3,050 1,388 3,05097 2,110 -0,264 2,110



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Bromdichlormethan

DIN 38402 A45

61

0,411 - 0,934 µg/l (|Zu-Score| < 2,00)



19,82% (Limited)

19,82%

0,128 µg/l

ProLab 2009

Labor

27 146 42 110

145 50 18 72 43 88 148 39 136

121 64 80 81 96 58 123 6 85 15 90 93 2 56 139

102

122 34 33 10 109 73 60 112

143 97 130 40 135 9

132 44 144 84 21 22 62 69 30 41 51 57 94 113

133 53 134 95

µg/l

1,8

1,6

1,4

1,2

1

0,8

0,6

0,4

0,2

Mittelw

ert

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Bromdichlormethan

DIN 38402 A45

61

0,411 - 0,934 µg/l (|Zu-Score| < 2,00)



19,82% (Limited)

19,82%

0,128 µg/l


10 0,650 0,023 0,650102 0,629 -0,150 0,629109 0,650 0,023 0,650110 0,495 -1,287 0,495112 0,667 0,142 0,667113 0,976 2,294 0,976121 0,560 -0,735 0,560122 0,630 -0,141 0,630123 0,580 -0,566 0,580130 0,690 0,302 0,690132 0,710 0,441 0,710133 0,980 2,322 0,980134 1,030 2,670 1,030135 0,693 0,323 0,693136 0,559 -0,744 0,559139 0,628 -0,158 0,628143 0,670 0,163 0,670144 0,733 0,602 0,733145 0,500 -1,245 0,500146 0,253 -3,341 0,253148 0,539 -0,914 0,53915 0,610 -0,311 0,61018 0,510 -1,160 0,5102 0,620 -0,226 0,62021 0,750 0,720 0,75022 0,750 0,720 0,75027 0,240 -3,452 0,24030 0,790 0,999 0,79033 0,640 -0,056 0,64034 0,630 -0,141 0,63039 0,540 -0,905 0,54040 0,690 0,302 0,69041 0,850 1,416 0,85042 0,400 -2,094 0,40043 0,530 -0,990 0,53044 0,710 0,441 0,71050 0,500 -1,245 0,50051 0,850 1,416 0,85053 1,020 2,600 1,02056 0,620 -0,226 0,62057 0,900 1,765 0,90058 0,577 -0,591 0,577


6 0,590 -0,481 0,59060 0,660 0,093 0,66062 0,750 0,720 0,75064 0,560 -0,735 0,56069 0,750 0,720 0,75072 0,520 -1,075 0,52073 0,650 0,023 0,65080 0,560 -0,735 0,56081 0,560 -0,735 0,56084 0,738 0,633 0,73885 0,600 -0,396 0,60088 0,530 -0,990 0,5309 0,700 0,372 0,70090 0,610 -0,311 0,61093 0,615 -0,269 0,61594 0,948 2,099 0,94895 1,820 8,172 1,82096 0,570 -0,651 0,57097 0,680 0,232 0,680



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Dibromchlormethan

DIN 38402 A45

60

2,485 - 4,335 µg/l (|Zu-Score| < 2,00)



13,68% (Limited)

13,68%

0,458 µg/l

ProLab 2009

Labor

146 18 27 110

148 39 121 72 144

123 50 2

145

139 64 33 43 80 85 134 96 112 34 93 122 58 62 60 6

130 56 143

113 15 135

136 9 97 90 40 88 22 44 73 10 57 109 69 133 42 30 53 94 132

102 21 84 51 95 41

µg/l

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Dibromchlormethan

DIN 38402 A45

60

2,485 - 4,335 µg/l (|Zu-Score| < 2,00)



13,68% (Limited)

13,68%

0,458 µg/l


10 3,610 0,533 3,610102 3,970 1,262 3,970109 3,650 0,614 3,650110 2,582 -1,776 2,582112 3,240 -0,248 3,240113 3,413 0,134 3,413121 2,810 -1,246 2,810122 3,250 -0,225 3,250123 2,880 -1,084 2,880130 3,310 -0,086 3,310132 3,900 1,120 3,900133 3,700 0,715 3,700134 3,150 -0,457 3,150135 3,475 0,259 3,475136 3,500 0,310 3,500139 3,060 -0,666 3,060143 3,400 0,108 3,400144 2,870 -1,107 2,870145 3,050 -0,689 3,050146 1,625 -3,997 1,625148 2,690 -1,525 2,69015 3,430 0,168 3,43018 1,990 -3,150 1,9902 3,000 -0,805 3,00021 4,020 1,363 4,02022 3,550 0,411 3,55027 2,310 -2,407 2,31030 3,830 0,978 3,83033 3,100 -0,573 3,10034 3,240 -0,248 3,24039 2,750 -1,386 2,75040 3,530 0,371 3,53041 6,000 5,372 6,00042 3,700 0,715 3,70043 3,100 -0,573 3,10044 3,560 0,432 3,56050 2,930 -0,968 2,93051 4,080 1,485 4,08053 3,840 0,999 3,84056 3,310 -0,086 3,31057 3,630 0,573 3,63058 3,270 -0,178 3,270


6 3,300 -0,109 3,30060 3,290 -0,132 3,29062 3,270 -0,178 3,27064 3,090 -0,596 3,09069 3,690 0,695 3,69072 2,830 -1,200 2,83073 3,600 0,513 3,60080 3,107 -0,557 3,10784 4,070 1,464 4,07085 3,120 -0,527 3,12088 3,540 0,391 3,5409 3,500 0,310 3,50090 3,510 0,330 3,51093 3,240 -0,248 3,24094 3,861 1,041 3,86195 4,090 1,505 4,09096 3,210 -0,318 3,21097 3,500 0,310 3,500



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Tetrachlorethen

DIN 38402 A45

60

3,985 - 8,238 µg/l (|Zu-Score| < 2,00)



17,67% (Limited)

17,67%

1,047 µg/l

ProLab 2009

Labor

109

132 18 72 2 73 146 39 144 33 110

139 43 145 80 58 112 93 122 64 130

148 6

123 62 10 135 81 15 88 95 50 21 97 53 113 42 121 34 56 60 22 96 143 30 27 102 9 40 44 136 57 133 85 69 84 51 41 94 134

µg/l

15

14

13

12

11

10

9

8

7

6

5

4

3

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Tetrachlorethen

DIN 38402 A45

60

3,985 - 8,238 µg/l (|Zu-Score| < 2,00)



17,67% (Limited)

17,67%

1,047 µg/l


10 5,820 -0,107 5,820102 6,670 0,645 6,670109 3,220 -2,789 3,220110 5,224 -0,722 5,224112 5,510 -0,427 5,510113 6,091 0,144 6,091121 6,250 0,282 6,250122 5,530 -0,407 5,530123 5,650 -0,283 5,650130 5,640 -0,293 5,640132 3,800 -2,190 3,800133 7,500 1,362 7,500134 15,110 7,940 15,110135 5,827 -0,100 5,827136 6,930 0,869 6,930139 5,234 -0,712 5,234143 6,450 0,454 6,450144 4,748 -1,213 4,748145 5,350 -0,592 5,350146 4,425 -1,546 4,425148 5,640 -0,293 5,64015 5,890 -0,035 5,89018 3,830 -2,160 3,8302 4,200 -1,778 4,20021 6,010 0,074 6,01022 6,400 0,411 6,40027 6,490 0,489 6,49030 6,450 0,454 6,45033 4,840 -1,118 4,84034 6,280 0,308 6,28039 4,730 -1,231 4,73040 6,870 0,818 6,87041 8,730 2,425 8,73042 6,150 0,195 6,15043 5,300 -0,644 5,30044 6,890 0,835 6,89050 5,970 0,040 5,97051 8,460 2,192 8,46053 6,080 0,135 6,08056 6,280 0,308 6,28057 7,490 1,353 7,49058 5,501 -0,436 5,501


6 5,640 -0,293 5,64060 6,280 0,308 6,28062 5,780 -0,149 5,78064 5,530 -0,407 5,53069 7,930 1,734 7,93072 4,090 -1,891 4,09073 4,360 -1,613 4,36080 5,467 -0,471 5,46781 5,850 -0,077 5,85084 8,055 1,842 8,05585 7,920 1,725 7,92088 5,910 -0,015 5,9109 6,820 0,774 6,82093 5,510 -0,427 5,51094 9,904 3,440 9,90495 5,910 -0,015 5,91096 6,430 0,437 6,43097 6,040 0,100 6,040



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Tribrommethan

DIN 38402 A45

61

3,288 - 5,611 µg/l (|Zu-Score| < 2,00)



13,17% (Limited)

13,17%

0,576 µg/l

ProLab 2009

Labor

146 18 39 134

110

148 27 72 64 81 123 33 62 88 96 93 144 2 43 121

130

122

139 10 60 40 58 34 132 50 85 6 57 143

112

135 56 22 97 80 15 53 90 9 21 73 113 42 133 30 51 102

145 44 95 136 94 109 84 69 41

µg/l

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Tribrommethan

DIN 38402 A45

61

3,288 - 5,611 µg/l (|Zu-Score| < 2,00)



13,17% (Limited)

13,17%

0,576 µg/l


10 4,200 -0,319 4,200102 4,990 0,997 4,990109 5,310 1,513 5,310110 3,643 -1,345 3,643112 4,415 0,068 4,415113 4,689 0,510 4,689121 4,050 -0,595 4,050122 4,140 -0,429 4,140123 3,870 -0,927 3,870130 4,120 -0,466 4,120132 4,300 -0,135 4,300133 4,900 0,851 4,900134 3,460 -1,682 3,460135 4,416 0,069 4,416136 5,170 1,287 5,170139 4,198 -0,323 4,198143 4,410 0,060 4,410144 3,993 -0,700 3,993145 5,000 1,013 5,000146 1,800 -4,741 1,800148 3,690 -1,259 3,69015 4,560 0,302 4,56018 2,700 -3,083 2,7002 4,000 -0,687 4,00021 4,650 0,447 4,65022 4,500 0,205 4,50027 3,790 -1,074 3,79030 4,920 0,883 4,92033 3,890 -0,890 3,89034 4,290 -0,153 4,29039 3,340 -1,903 3,34040 4,250 -0,227 4,25041 5,930 2,515 5,93042 4,690 0,512 4,69043 4,000 -0,687 4,00044 5,020 1,045 5,02050 4,330 -0,079 4,33051 4,940 0,916 4,94053 4,570 0,318 4,57056 4,450 0,124 4,45057 4,380 0,011 4,38058 4,265 -0,199 4,265


6 4,370 -0,006 4,37060 4,220 -0,282 4,22062 3,910 -0,853 3,91064 3,810 -1,037 3,81069 5,360 1,594 5,36072 3,790 -1,074 3,79073 4,670 0,480 4,67080 4,550 0,286 4,55081 3,830 -1,001 3,83084 5,340 1,562 5,34085 4,360 -0,024 4,36088 3,920 -0,835 3,9209 4,600 0,367 4,60090 4,580 0,334 4,58093 3,950 -0,780 3,95094 5,200 1,336 5,20095 5,040 1,077 5,04096 3,920 -0,835 3,92097 4,520 0,237 4,520



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Trichlorethen

DIN 38402 A45

60

5,007 - 11,753 µg/l (|Zu-Score| < 2,00)



20,55% (Limited)

20,55%

1,651 µg/l

ProLab 2009

Labor

146 18 39 72 73 2

132 43 148

144

112

130 64 93 139 15 33 81 121

123

122

135 62 97 145 58 6 95 102 80 10 27 42 53 96 109 60 143

110 34 50 136 88 40 113 30 44 22 9 21 56 85 133

134 69 57 84 94 41 51

µg/l

13

12

11

10

9

8

7

6

5

4

3

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Trichlorethen

DIN 38402 A45

60

5,007 - 11,753 µg/l (|Zu-Score| < 2,00)



20,55% (Limited)

20,55%

1,651 µg/l


10 7,970 -0,043 7,970102 7,810 -0,149 7,810109 8,360 0,175 8,360110 8,524 0,263 8,524112 6,556 -0,977 6,556113 8,792 0,407 8,792121 7,340 -0,459 7,340122 7,450 -0,386 7,450123 7,430 -0,399 7,430130 6,690 -0,888 6,690132 6,200 -1,212 6,200133 9,800 0,950 9,800134 9,810 0,955 9,810135 7,470 -0,373 7,470136 8,700 0,358 8,700139 7,079 -0,631 7,079143 8,430 0,213 8,430144 6,554 -0,978 6,554145 7,550 -0,320 7,550146 2,650 -3,557 2,650148 6,340 -1,119 6,34015 7,160 -0,578 7,16018 4,440 -2,374 4,4402 6,180 -1,225 6,18021 9,700 0,896 9,70022 9,500 0,788 9,50027 8,040 0,003 8,04030 8,840 0,433 8,84033 7,250 -0,518 7,25034 8,530 0,266 8,53039 5,450 -1,707 5,45040 8,720 0,369 8,72041 11,500 1,864 11,50042 8,150 0,062 8,15043 6,300 -1,146 6,30044 9,320 0,691 9,32050 8,650 0,331 8,65051 11,870 2,063 11,87053 8,190 0,083 8,19056 9,740 0,917 9,74057 10,350 1,245 10,35058 7,592 -0,292 7,592


6 7,690 -0,228 7,69060 8,420 0,207 8,42062 7,500 -0,353 7,50064 6,830 -0,796 6,83069 10,200 1,165 10,20072 5,580 -1,621 5,58073 5,780 -1,489 5,78080 7,943 -0,061 7,94381 7,260 -0,512 7,26084 11,120 1,660 11,12085 9,770 0,933 9,77088 8,700 0,358 8,7009 9,680 0,885 9,68093 6,900 -0,750 6,90094 11,390 1,805 11,39095 7,790 -0,162 7,79096 8,330 0,159 8,33097 7,500 -0,353 7,500



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Trichlormethan

DIN 38402 A45

61

0,843 - 1,637 µg/l (|Zu-Score| < 2,00)



16,22% (Limited)

16,22%

0,196 µg/l

ProLab 2009

Labor

146 18 72 90 27 80 43 58 10 145 73 148 93 139 22 62 88 39 112

113 9

123 56 110

122

134 50 132 2 34 143 64 15 33 60 130

136 81 121

144 6 97 135 96 40 95 42 102 30 69 85 84 133 21 41 57 53 94 109 51 44

µg/l

21,91,81,71,61,51,41,3

1,21,1

10,90,80,70,60,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


E

Trichlormethan

DIN 38402 A45

61

0,843 - 1,637 µg/l (|Zu-Score| < 2,00)



16,22% (Limited)

16,22%

0,196 µg/l


10 1,050 -0,864 1,050102 1,350 0,664 1,350109 1,850 2,995 1,850110 1,118 -0,491 1,118112 1,098 -0,601 1,098113 1,098 -0,601 1,098121 1,240 0,151 1,240122 1,120 -0,481 1,120123 1,110 -0,535 1,110130 1,230 0,104 1,230132 1,200 -0,042 1,200133 1,500 1,363 1,500134 1,190 -0,097 1,190135 1,290 0,384 1,290136 1,230 0,104 1,230139 1,075 -0,727 1,075143 1,210 0,011 1,210144 1,268 0,281 1,268145 1,050 -0,864 1,050146 0,565 -3,523 0,565148 1,060 -0,809 1,06015 1,220 0,058 1,22018 0,670 -2,948 0,6702 1,200 -0,042 1,20021 1,580 1,736 1,58022 1,080 -0,700 1,08027 0,980 -1,248 0,98030 1,360 0,710 1,36033 1,220 0,058 1,22034 1,200 -0,042 1,20039 1,090 -0,645 1,09040 1,300 0,431 1,30041 1,600 1,829 1,60042 1,340 0,617 1,34043 0,990 -1,193 0,99044 1,890 3,182 1,89050 1,190 -0,097 1,19051 1,850 2,995 1,85053 1,630 1,969 1,63056 1,110 -0,535 1,11057 1,610 1,876 1,61058 1,029 -0,979 1,029


6 1,270 0,291 1,27060 1,220 0,058 1,22062 1,080 -0,700 1,08064 1,210 0,011 1,21069 1,360 0,710 1,36072 0,940 -1,467 0,94073 1,050 -0,864 1,05080 0,981 -1,243 0,98181 1,230 0,104 1,23084 1,400 0,897 1,40085 1,360 0,710 1,36088 1,080 -0,700 1,0809 1,100 -0,590 1,10090 0,960 -1,358 0,96093 1,070 -0,755 1,07094 1,682 2,212 1,68295 1,300 0,431 1,30096 1,290 0,384 1,29097 1,280 0,337 1,280


Vergleichs-STD











Ringversuchskenndaten Charge F



FProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


102102102102102102102102109109109109109109109109

1111111111111111

110110110110110110110110111111111111111111111111

112112112112112112112112113113113113113113113113

1212121212121212122122122122122122122122

124124124124124124124125125125125125125125125

128129129129129129129129129

130130130130130130130130

133133133133133133133133135135135135135135135135

136136136136136136136136137137137137137137137137

138138138138138138138138139139139139139139139139

141141141141141141141141143143143143143143143143

146146146146146146146146150150150150150150150150

1616161616161616

19191919191919192323232323232323

24242424242424242828282828282828

19,03

3,49

3,16

2,60

2,15

2,16

57,81

2,28

4,62

2,28

2,45

-2,89

-3,88

-2,49

-2,70

-2,55

-4,45

-2,30

-3,21

quo data



FProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


4545454545454545

4747474747474747484848484848484949494949494949545454545454545457575757575757575959595959595959

60606060606060606161616161616161636363636363636365656565656565656666666666666666

777777777070707070707070737373737373737374747474747474747676767676767676

79797979797979798282828282828282838383838383838384848484848484848686868686868686898989898989

919191919191919192929292929292929797979797979797989999999999999999

2,01

2,23

2,65

4,41

4,17

5,08

2,123,202,50

3,402,65

2,14

3,462,89

3,17

2,13

3,52

2,20

2,14

38,58

-2,09

-2,01

-2,81

-2,30

-2,16

quo data



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

1,2-Dichlorethan

DIN 38402 A45

59

2,644 - 5,594 µg/l (|Zu-Score| < 2,00)



18,20% (Limited)

18,20%

0,725 µg/l

ProLab 2009

Labor

28 146 16 86 138 61 66 35 49 141 99 139 36 133 73 112 65 7 31 113

130

125

110 63 83 54 122 74 11 19 59 60 76 12 47 84 143 97 129

136 23 79 101

109

150 4 48 102 57 135 70 92 137 45 82 91 24 124

111

µg/l

8

7

6

5

4

3

2

1

0

Mittelw

ert

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

1,2-Dichlorethan

DIN 38402 A45

59

2,644 - 5,594 µg/l (|Zu-Score| < 2,00)



18,20% (Limited)

18,20%

0,725 µg/l


101 4,300 0,391 4,300102 4,600 0,764 4,600109 4,400 0,516 4,40011 3,940 -0,068 3,940110 3,810 -0,261 3,810111 19,290 19,026 19,290112 3,637 -0,519 3,637113 3,712 -0,408 3,71212 4,080 0,118 4,080122 3,900 -0,127 3,900124 6,790 3,487 6,790125 3,790 -0,291 3,790129 4,140 0,192 4,140130 3,730 -0,381 3,730133 3,600 -0,575 3,600135 4,733 0,929 4,733136 4,160 0,217 4,160137 5,236 1,555 5,236138 2,970 -1,514 2,970139 3,511 -0,707 3,511141 3,430 -0,828 3,430143 4,110 0,155 4,110146 2,050 -2,885 2,050150 4,494 0,632 4,49416 2,740 -1,857 2,74019 3,950 -0,053 3,95023 4,160 0,217 4,16024 6,530 3,163 6,53028 1,382 -3,881 1,38231 3,672 -0,467 3,67235 3,238 -1,114 3,23836 3,590 -0,589 3,5904 4,550 0,702 4,55045 5,600 2,007 5,60047 4,100 0,143 4,10048 4,580 0,739 4,58049 3,290 -1,037 3,29054 3,890 -0,142 3,89057 4,700 0,888 4,70059 3,970 -0,023 3,97060 4,000 0,018 4,00061 3,170 -1,216 3,170


63 3,860 -0,187 3,86065 3,654 -0,494 3,65466 3,210 -1,156 3,2107 3,670 -0,470 3,67070 4,880 1,112 4,88073 3,620 -0,545 3,62074 3,930 -0,082 3,93076 4,070 0,105 4,07079 4,240 0,317 4,24082 5,780 2,231 5,78083 3,860 -0,187 3,86084 4,105 0,149 4,10586 2,831 -1,721 2,83191 6,120 2,654 6,12092 5,100 1,386 5,10097 4,110 0,155 4,11099 3,500 -0,724 3,500



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Benzol

DIN 38402 A45

58

0,313 - 0,901 µg/l (|Zu-Score| < 2,00)



25,00% (Limited)

26,07%

0,149 µg/l

ProLab 2009

Labor

146 16 112 70 49 129 83 76 111

110 63 125

141 36 136 31 59 122

143

150 66 100

139 97 65 130 61 54 23 74 135 11 60 12 19 47 7

128

138 79 99 102 73 101 24 91 57 4 84 133 92 113

137

109 82 45 86 28

µg/l

1,5

1,4

1,3

1,2

1,1

1

0,9

0,8

0,7

0,6

0,5

0,4

0,3

0,2

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Benzol

DIN 38402 A45

58

0,313 - 0,901 µg/l (|Zu-Score| < 2,00)



25,00% (Limited)

26,07%

0,149 µg/l


100 0,520 -0,389 0,520101 0,658 0,532 0,658102 0,641 0,429 0,641109 1,000 2,600 1,00011 0,585 0,090 0,585110 0,462 -0,839 0,462111 0,450 -0,932 0,450112 0,395 -1,360 0,395113 0,926 2,153 0,92612 0,610 0,241 0,610122 0,510 -0,467 0,510124125 0,498 -0,560 0,498128 0,620 0,302 0,620129 0,430 -1,088 0,430130 0,530 -0,311 0,530133 0,900 1,995 0,900135 0,574 0,024 0,574136 0,502 -0,529 0,502137 0,928 2,165 0,928138 0,620 0,302 0,620139 0,520 -0,389 0,520141 0,500 -0,544 0,500143 0,510 -0,467 0,510146 0,250 -2,485 0,250150 0,510 -0,467 0,51016 0,345 -1,748 0,34519 0,610 0,241 0,61023 0,560 -0,078 0,56024 0,660 0,544 0,66028 10,128 57,809 10,12831 0,503 -0,521 0,50336 0,500 -0,544 0,5004 0,850 1,693 0,85045 1,300 4,415 1,30047 0,610 0,241 0,61049 0,410 -1,243 0,41054 0,550 -0,156 0,55057 0,760 1,149 0,76059 0,505 -0,505 0,50560 0,590 0,120 0,59061 0,530 -0,311 0,530


63 0,465 -0,816 0,46565 0,521 -0,381 0,52166 0,510 -0,467 0,5107 0,610 0,241 0,61070 0,400 -1,321 0,40073 0,650 0,483 0,65074 0,570 -0,001 0,57076 0,440 -1,010 0,44079 0,620 0,302 0,62082 1,260 4,173 1,26083 0,430 -1,088 0,43084 0,873 1,832 0,87386 1,410 5,080 1,41091 0,750 1,088 0,75092 0,920 2,116 0,92097 0,520 -0,389 0,52099 0,620 0,302 0,620



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Bromdichlormethan

DIN 38402 A45

60

4,718 - 7,614 µg/l (|Zu-Score| < 2,00)



11,82% (Limited)

11,82%

0,719 µg/l

ProLab 2009

Labor

48 61 16 63 150 66 7 73 141

110 89 65 146 99 86 36 49 28 79 139 54 45 47 135

130 31 83 133

122

143 24 4 35 112 59 60 19 11 101

113 74 138 12 70 97 109

102

125

129

136 84 76 137 82 57 111

124 23 92 91

µg/l

9

8,5

8

7,5

7

6,5

6

5,5

5

4,5

4

Mitte

lwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Bromdichlormethan

DIN 38402 A45

60

4,718 - 7,614 µg/l (|Zu-Score| < 2,00)



11,82% (Limited)

11,82%

0,719 µg/l


101 6,310 0,299 6,310102 6,570 0,638 6,570109 6,490 0,534 6,49011 6,240 0,208 6,240110 5,463 -0,907 5,463111 7,446 1,781 7,446112 6,058 -0,033 6,058113 6,316 0,307 6,31612 6,410 0,430 6,410122 6,010 -0,104 6,010124 7,500 1,852 7,500125 6,630 0,717 6,630129 6,740 0,860 6,740130 5,930 -0,221 5,930133 6,000 -0,118 6,000135 5,913 -0,246 5,913136 6,750 0,873 6,750137 6,837 0,987 6,837138 6,370 0,378 6,370139 5,722 -0,526 5,722141 5,460 -0,911 5,460143 6,010 -0,104 6,010146 5,550 -0,779 5,550150 5,206 -1,284 5,20616 4,920 -1,704 4,92019 6,190 0,143 6,19023 7,830 2,282 7,83024 6,010 -0,104 6,01028 5,705 -0,551 5,70531 5,952 -0,189 5,95235 6,048 -0,048 6,04836 5,640 -0,647 5,6404 6,040 -0,060 6,04045 5,900 -0,265 5,90047 5,900 -0,265 5,90048 4,655 -2,093 4,65549 5,650 -0,632 5,65054 5,840 -0,353 5,84057 7,180 1,434 7,18059 6,070 -0,016 6,07060 6,110 0,038 6,11061 4,790 -1,895 4,790


63 5,170 -1,337 5,17065 5,501 -0,851 5,50166 5,310 -1,131 5,3107 5,400 -0,999 5,40070 6,410 0,430 6,41073 5,420 -0,970 5,42074 6,350 0,351 6,35076 6,830 0,978 6,83079 5,720 -0,529 5,72082 7,170 1,421 7,17083 5,970 -0,162 5,97084 6,758 0,884 6,75886 5,611 -0,689 5,61189 5,500 -0,852 5,50091 8,530 3,195 8,53092 8,000 2,504 8,00097 6,420 0,443 6,42099 5,600 -0,706 5,600



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Dibromchlormethan

DIN 38402 A45

60

5,223 - 8,106 µg/l (|Zu-Score| < 2,00)



10,88% (Limited)

10,88%

0,716 µg/l

ProLab 2009

Labor

110 48 61 89 63 7 16 150 65 146

133 99 73 139 23 49 66 112

130

113 28 35 24 11 4

122 45 36 60 143 83 47 74 54 70 31 125

135

101 19 79 129 12 141

136 57 97 59 76 109

138 84 102

124 86 111 82 92 91 137

µg/l

10

9,5

9

8,5

8

7,5

7

6,5

6

5,5

5

4,5

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Dibromchlormethan

DIN 38402 A45

60

5,223 - 8,106 µg/l (|Zu-Score| < 2,00)



10,88% (Limited)

10,88%

0,716 µg/l


101 6,780 0,255 6,780102 7,760 1,545 7,760109 7,340 0,992 7,34011 6,440 -0,215 6,440110 4,745 -2,702 4,745111 7,818 1,621 7,818112 6,200 -0,567 6,200113 6,295 -0,427 6,29512 6,830 0,321 6,830122 6,500 -0,126 6,500124 7,770 1,558 7,770125 6,730 0,189 6,730129 6,810 0,295 6,810130 6,280 -0,449 6,280133 6,000 -0,860 6,000135 6,761 0,230 6,761136 7,020 0,571 7,020137 10,096 4,620 10,096138 7,550 1,269 7,550139 6,086 -0,734 6,086141 6,860 0,360 6,860143 6,550 -0,053 6,550146 5,975 -0,897 5,975150 5,892 -1,019 5,89216 5,805 -1,146 5,80519 6,790 0,268 6,79023 6,150 -0,640 6,15024 6,410 -0,259 6,41028 6,295 -0,427 6,29531 6,707 0,159 6,70735 6,384 -0,297 6,38436 6,530 -0,082 6,5304 6,440 -0,215 6,44045 6,500 -0,126 6,50047 6,600 0,018 6,60048 5,270 -1,931 5,27049 6,160 -0,625 6,16054 6,650 0,084 6,65057 7,070 0,637 7,07059 7,260 0,887 7,26060 6,540 -0,068 6,54061 5,410 -1,726 5,410


63 5,580 -1,477 5,58065 5,948 -0,937 5,94866 6,160 -0,625 6,1607 5,760 -1,212 5,76070 6,690 0,137 6,69073 6,020 -0,831 6,02074 6,600 0,018 6,60076 7,300 0,940 7,30079 6,790 0,268 6,79082 7,890 1,716 7,89083 6,560 -0,038 6,56084 7,685 1,446 7,68586 7,779 1,570 7,77989 5,500 -1,594 5,50091 9,170 3,401 9,17092 8,600 2,651 8,60097 7,090 0,663 7,09099 6,000 -0,860 6,000



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Tetrachlorethen

DIN 38402 A45

60

5,515 - 11,375 µg/l (|Zu-Score| < 2,00)



17,62% (Limited)

17,62%

1,442 µg/l

ProLab 2009

Labor

86 109 73 16 7 61 141 31 150

146

112 48 49 137 59 139

111

110

101

135 89 130 65 122 79 63 4 99 97 125

133 70 74 19 28 54 36 45 113 76 60 83 138

143 82 11 47 102 24 12 136 35 91 23 57 124

129 84 66 92

µg/l

14

13

12

11

10

9

8

7

6

5

4

Mittelw

ertToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Tetrachlorethen

DIN 38402 A45

60

5,515 - 11,375 µg/l (|Zu-Score| < 2,00)



17,62% (Limited)

17,62%

1,442 µg/l


101 7,440 -0,560 7,440102 9,330 0,716 9,330109 4,780 -2,550 4,78011 9,060 0,547 9,060110 7,430 -0,567 7,430111 7,338 -0,636 7,338112 7,094 -0,819 7,094113 8,571 0,240 8,57112 9,620 0,898 9,620122 7,770 -0,313 7,770124 10,550 1,482 10,550125 8,150 -0,029 8,150129 10,770 1,620 10,770130 7,650 -0,403 7,650133 8,200 0,007 8,200135 7,473 -0,535 7,473136 9,630 0,905 9,630137 7,222 -0,723 7,222138 8,870 0,428 8,870139 7,282 -0,678 7,282141 6,740 -1,084 6,740143 8,950 0,478 8,950146 7,050 -0,852 7,050150 6,993 -0,894 6,99316 5,975 -1,656 5,97519 8,310 0,076 8,31023 10,450 1,419 10,45024 9,600 0,886 9,60028 8,340 0,095 8,34031 6,882 -0,977 6,88235 9,894 1,070 9,89436 8,430 0,152 8,4304 7,860 -0,246 7,86045 8,500 0,196 8,50047 9,300 0,698 9,30048 7,115 -0,803 7,11549 7,190 -0,747 7,19054 8,350 0,102 8,35057 10,470 1,432 10,47059 7,230 -0,717 7,23060 8,610 0,265 8,61061 6,540 -1,233 6,540


63 7,800 -0,290 7,80065 7,763 -0,318 7,76366 11,600 2,141 11,6007 6,520 -1,248 6,52070 8,220 0,020 8,22073 5,500 -2,011 5,50074 8,230 0,026 8,23076 8,580 0,246 8,58079 7,780 -0,305 7,78082 8,960 0,484 8,96083 8,630 0,277 8,63084 10,930 1,721 10,93086 4,435 -2,808 4,43589 7,500 -0,515 7,50091 9,990 1,131 9,99092 13,700 3,459 13,70097 8,030 -0,118 8,03099 7,900 -0,216 7,900



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Tribrommethan

DIN 38402 A45

60

7,007 - 12,083 µg/l (|Zu-Score| < 2,00)



13,41% (Limited)

13,41%

1,258 µg/l

ProLab 2009

Labor

86 7 63 146 36 110 61 66 11 112 4 65 99 49 28 141 16 48 130 73 54 35 139

122

133 89 60 47 135

143 24 150 70 101

125 12 79 137 31 83 19 97 82 45 113

129 57 124

136 76 102

109 74 84 92 138 59 23 111 91

µg/l

14

13

12

11

10

9

8

7

6

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Tribrommethan

DIN 38402 A45

60

7,007 - 12,083 µg/l (|Zu-Score| < 2,00)



13,41% (Limited)

13,41%

1,258 µg/l


101 9,580 0,151 9,580102 10,600 0,904 10,600109 10,700 0,978 10,70011 8,240 -0,959 8,240110 7,719 -1,399 7,719111 12,460 2,278 12,460112 8,337 -0,877 8,337113 10,010 0,469 10,01012 9,670 0,218 9,670122 8,960 -0,351 8,960124 10,350 0,720 10,350125 9,630 0,188 9,630129 10,020 0,476 10,020130 8,870 -0,427 8,870133 9,000 -0,317 9,000135 9,265 -0,093 9,265136 10,460 0,801 10,460137 9,733 0,264 9,733138 11,380 1,481 11,380139 8,934 -0,373 8,934141 8,720 -0,554 8,720143 9,290 -0,072 9,290146 7,650 -1,457 7,650150 9,353 -0,019 9,35316 8,775 -0,507 8,77519 9,840 0,343 9,84023 11,870 1,843 11,87024 9,340 -0,030 9,34028 8,705 -0,566 8,70531 9,768 0,290 9,76835 8,907 -0,396 8,90736 7,650 -1,457 7,6504 8,340 -0,875 8,34045 10,000 0,461 10,00047 9,200 -0,148 9,20048 8,825 -0,465 8,82549 8,590 -0,663 8,59054 8,900 -0,402 8,90057 10,080 0,520 10,08059 11,400 1,495 11,40060 9,020 -0,300 9,02061 7,780 -1,348 7,780


63 7,360 -1,702 7,36065 8,363 -0,855 8,36366 8,220 -0,976 8,2207 7,290 -1,761 7,29070 9,480 0,077 9,48073 8,880 -0,418 8,88074 10,710 0,986 10,71076 10,560 0,875 10,56079 9,690 0,232 9,69082 9,960 0,432 9,96083 9,810 0,321 9,81084 10,710 0,986 10,71086 7,134 -1,893 7,13489 9,000 -0,317 9,00091 13,290 2,891 13,29092 11,300 1,422 11,30097 9,940 0,417 9,94099 8,500 -0,739 8,500



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Trichlorethen

DIN 38402 A45

60

3,505 - 6,901 µg/l (|Zu-Score| < 2,00)



16,54% (Limited)

16,54%

0,837 µg/l

ProLab 2009

Labor

146 31 73 16 63 130

141

112 61 7 86 36 139 19 110 76 65 97 122 49 82 89 150 4 28 125

102

135 45 113

101 48 133 99 74 54 111 70 79 60 143

138 23 47 83 59 35 24 109 12 66 11 136

129

137 91 84 124 57 92

µg/l

8

7,5

7

6,5

6

5,5

5

4,5

4

3,5

3

2,5

2

1,5

Mitte

lwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Trichlorethen

DIN 38402 A45

60

3,505 - 6,901 µg/l (|Zu-Score| < 2,00)



16,54% (Limited)

16,54%

0,837 µg/l


101 4,940 -0,158 4,940102 4,880 -0,235 4,880109 5,620 0,606 5,62011 5,850 0,856 5,850110 4,584 -0,615 4,584111 5,326 0,286 5,326112 4,144 -1,180 4,144113 4,924 -0,179 4,92412 5,660 0,650 5,660122 4,780 -0,363 4,780124 7,310 2,445 7,310125 4,860 -0,261 4,860129 6,060 1,085 6,060130 4,120 -1,211 4,120133 5,200 0,149 5,200135 4,898 -0,212 4,898136 5,870 0,878 5,870137 6,525 1,591 6,525138 5,450 0,421 5,450139 4,487 -0,740 4,487141 4,130 -1,198 4,130143 5,410 0,377 5,410146 1,600 -4,446 1,600150 4,826 -0,304 4,82616 3,800 -1,621 3,80019 4,550 -0,659 4,55023 5,450 0,421 5,45024 5,610 0,595 5,61028 4,855 -0,267 4,85531 3,272 -2,299 3,27235 5,602 0,586 5,60236 4,480 -0,749 4,4804 4,830 -0,299 4,83045 4,900 -0,209 4,90047 5,500 0,475 5,50048 5,080 0,018 5,08049 4,790 -0,351 4,79054 5,310 0,269 5,31057 7,980 3,174 7,98059 5,590 0,573 5,59060 5,400 0,367 5,40061 4,160 -1,159 4,160


63 3,820 -1,596 3,82065 4,705 -0,460 4,70566 5,840 0,845 5,8407 4,280 -1,005 4,28070 5,340 0,301 5,34073 3,600 -1,878 3,60074 5,300 0,258 5,30076 4,670 -0,505 4,67079 5,340 0,301 5,34082 4,800 -0,338 4,80083 5,520 0,497 5,52084 7,023 2,133 7,02386 4,353 -0,912 4,35389 4,800 -0,338 4,80091 6,840 1,934 6,84092 8,300 3,523 8,30097 4,730 -0,428 4,73099 5,200 0,149 5,200



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Trichlormethan

DIN 38402 A45

61

1,563 - 2,851 µg/l (|Zu-Score| < 2,00)



14,76% (Limited)

14,76%

0,319 µg/l

ProLab 2009

Labor

146 86 61 16 141 74 112 66 49 7

139

110 28 35 11 133 63 73 83 89 54 138 48 101

122 24 31 65 79 99 36 150 60 143 4 59 130

113 47 97 76 135 70 19 136

129

102 12 125 84 23 111 45 124 82 91 137

109 92 57 98

µg/l

3,2

3

2,8

2,6

2,4

2,2

2

1,8

1,6

1,4

1,2

1

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


F

Trichlormethan

DIN 38402 A45

61

1,563 - 2,851 µg/l (|Zu-Score| < 2,00)



14,76% (Limited)

14,76%

0,319 µg/l


101 2,050 -0,367 2,050102 2,380 0,638 2,380109 2,850 1,997 2,85011 1,970 -0,635 1,970110 1,950 -0,702 1,950111 2,556 1,147 2,556112 1,837 -1,080 1,837113 2,196 0,106 2,19612 2,400 0,696 2,400122 2,060 -0,333 2,060124 2,640 1,390 2,640125 2,430 0,782 2,430129 2,370 0,609 2,370130 2,170 0,031 2,170133 2,000 -0,534 2,000135 2,338 0,516 2,338136 2,360 0,580 2,360137 2,829 1,936 2,829138 2,020 -0,467 2,020139 1,903 -0,859 1,903141 1,690 -1,573 1,690143 2,140 -0,065 2,140146 1,200 -3,215 1,200150 2,123 -0,122 2,12316 1,630 -1,774 1,63019 2,350 0,551 2,35023 2,540 1,100 2,54024 2,060 -0,333 2,06028 1,955 -0,685 1,95531 2,066 -0,313 2,06635 1,955 -0,685 1,95536 2,120 -0,132 2,1204 2,140 -0,065 2,14045 2,600 1,274 2,60047 2,200 0,117 2,20048 2,030 -0,434 2,03049 1,880 -0,936 1,88054 2,010 -0,501 2,01057 2,920 2,199 2,92059 2,160 0,002 2,16060 2,130 -0,099 2,13061 1,610 -1,841 1,610


63 2,000 -0,534 2,00065 2,066 -0,313 2,06666 1,850 -1,037 1,8507 1,890 -0,903 1,89070 2,340 0,522 2,34073 2,000 -0,534 2,00074 1,810 -1,171 1,81076 2,320 0,464 2,32079 2,090 -0,233 2,09082 2,680 1,505 2,68083 2,000 -0,534 2,00084 2,490 0,956 2,49086 1,515 -2,159 1,51589 2,000 -0,534 2,00091 2,760 1,737 2,76092 2,900 2,141 2,90097 2,280 0,349 2,28098 15,500 38,576 15,50099 2,100 -0,199 2,100


Vergleichs-STD











Ringversuchskenndaten Charge G



GProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


100

101101101101101101101101102102102102102102102102

103103103103103103

107107107107107107107107111111111111111111111111

114114114114114114114114115

117117117117117117117117123123123123123123123123

1251251251251251251251251313131313131313

131131131131131131131131132132132132132132

134134134134134134134134

136136136136136136136136137137137137137137137137

138138138138138138138138139139139139139139139139

1414141414141414141141141141141141141141

142142142142142142142142145145145145145145145145

147147147147147147147147149149149149149149149149

150150150150150150150150

17171717171717172525252525252525

262626262626262629

17,36

2,07

2,40 2,76

2,92

4,02

35,14

2,59

2,12

-2,26

-2,01

-2,39

-7,28

-2,11

-3,41

-2,63

-3,06

quo data



GProbe:

-2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2 -2 0 2


32323232323232323737373737373737383838383838383855555555

585858585858585861616161616161616262626262626262636363636363636366666666666666667171717171717171

76767676767676767777777777777777797979797979797988888888

81818181818181

848484848484848485858585858585858686868686868686878787878787878888888888888888

898989898989909090909191919191919191929292929292929293939393939393939494949494949494

959595959595959596969696969696969797979797979797989999999999999999

3,232,57

2,22

3,41 2,09

2,802,99

2,55

2,903,36

2,884,44

3,73

2,06

2,412,594,37

2,93

2,52

132,08

-3,06

quo data



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

1,2-Dichlorethan

DIN 38402 A45

53

4,316 - 7,603 µg/l (|Zu-Score| < 2,00)



13,92% (Limited)

13,92%

0,814 µg/l

ProLab 2009

Labor

14 86 131

141

138

123 25 142 3 5 38 61 8 99 66 32 26 107

147 93 88 117 71 62 77 139

145

114 63 94 17 96 136 58 37 76 79 101

134 81 13 125

102 97 85 149 84 150

137 95 92 91 111

µg/l

9

8,5

8

7,5

7

6,5

6

5,5

5

4,5

4

3,5

3

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

1,2-Dichlorethan

DIN 38402 A45

53

4,316 - 7,603 µg/l (|Zu-Score| < 2,00)



13,92% (Limited)

13,92%

0,814 µg/l


101 6,250 0,460 6,250102 6,670 0,938 6,670107 5,490 -0,465 5,490111 21,100 17,360 21,100114 5,820 -0,033 5,820117 5,540 -0,400 5,540123 5,020 -1,080 5,020125 6,500 0,745 6,50013 6,450 0,688 6,450131 4,750 -1,433 4,750134 6,340 0,563 6,340136 6,010 0,187 6,010137 7,528 1,915 7,528138 4,890 -1,250 4,890139 5,648 -0,258 5,64814 4,380 -1,917 4,380141 4,770 -1,407 4,770142 5,200 -0,844 5,200145 5,700 -0,190 5,700147 5,510 -0,439 5,510149 7,120 1,450 7,120150 7,229 1,574 7,22917 5,947 0,116 5,94725 5,170 -0,883 5,17026 5,465 -0,498 5,4653 5,250 -0,779 5,25032 5,400 -0,583 5,40037 6,088 0,276 6,08838 5,279 -0,741 5,2795 5,250 -0,779 5,25058 6,019 0,197 6,01961 5,300 -0,713 5,30062 5,610 -0,308 5,61063 5,830 -0,020 5,83066 5,360 -0,635 5,36071 5,600 -0,321 5,60076 6,200 0,403 6,20077 5,640 -0,269 5,64079 6,220 0,426 6,2208 5,300 -0,713 5,30081 6,370 0,597 6,37084 7,173 1,511 7,173


85 6,850 1,143 6,85086 4,452 -1,822 4,45288 5,530 -0,413 5,53091 8,680 3,226 8,68092 8,100 2,566 8,10093 5,520 -0,426 5,52094 5,920 0,085 5,92095 7,800 2,224 7,80096 5,960 0,130 5,96097 6,710 0,984 6,71099 5,300 -0,713 5,300



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Benzol

DIN 38402 A45

58

0,958 - 2,285 µg/l (|Zu-Score| < 2,00)



20,90% (Limited)

20,90%

0,324 µg/l

ProLab 2009

Labor

115 3

141 61 123

131 14 77 25 136

100

125

142 93 150 63 71 134 32 8 58 139 38 111 79 81 107

117 97 26 76 62 37 29 147 99 101

114

138 5 66 88 102 95 145 1 85 96 137 86 91 94 92 149 84 17 13 87

µg/l

2,8

2,6

2,4

2,2

2

1,8

1,6

1,4

1,2

1

0,8

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Benzol

DIN 38402 A45

58

0,958 - 2,285 µg/l (|Zu-Score| < 2,00)



20,90% (Limited)

20,90%

0,324 µg/l


1 1,820 0,731 1,820100 1,300 -0,850 1,300101 1,610 0,157 1,610102 1,740 0,512 1,740107 1,470 -0,278 1,470111 1,438 -0,385 1,438114 1,610 0,157 1,610115 0,880 -2,263 0,880117 1,470 -0,278 1,470123 1,160 -1,321 1,160125 1,300 -0,850 1,30013 2,310 2,069 2,310131 1,200 -1,186 1,200134 1,390 -0,547 1,390136 1,280 -0,917 1,280137 2,039 1,329 2,039138 1,620 0,184 1,620139 1,415 -0,463 1,41514 1,230 -1,085 1,230141 1,110 -1,489 1,110142 1,300 -0,850 1,300145 1,800 0,676 1,800147 1,570 0,048 1,570149 2,230 1,851 2,230150 1,307 -0,826 1,30717 2,269 1,957 2,26925 1,240 -1,052 1,24026 1,495 -0,194 1,49529 1,560 0,020 1,5603 1,080 -1,590 1,08032 1,400 -0,513 1,40037 1,533 -0,066 1,53338 1,435 -0,396 1,4355 1,670 0,321 1,67058 1,411 -0,476 1,41161 1,150 -1,355 1,15062 1,530 -0,076 1,53063 1,320 -0,783 1,32066 1,690 0,376 1,69071 1,350 -0,682 1,35076 1,500 -0,177 1,50077 1,230 -1,085 1,230


79 1,450 -0,345 1,4508 1,400 -0,513 1,40081 1,460 -0,311 1,46084 2,248 1,900 2,24885 1,980 1,168 1,98086 2,130 1,577 2,13087 2,800 3,408 2,80088 1,710 0,430 1,71091 2,130 1,577 2,13092 2,200 1,769 2,20093 1,300 -0,850 1,30094 2,136 1,594 2,13695 1,760 0,567 1,76096 2,000 1,222 2,00097 1,470 -0,278 1,47099 1,600 0,130 1,600



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Bromdichlormethan

DIN 38402 A45

59

6,334 - 10,502 µg/l (|Zu-Score| < 2,00)



12,48% (Limited)

12,48%

1,034 µg/l

ProLab 2009

Labor

145 14 3

141 25 142 61 63 5

150

123 62 66 93 79 88 38 37 81 77 32 86 101 58 89 99 26 107 85 147

103 71 117 13 139

149

131

114

132 17 102

138 8

125 1 90 136

137 94 97 76 96 84 95 134 87 111 91 92

µg/l

12

11,5

11

10,5

10

9,5

9

8,5

8

7,5

7

6,5

6

5,5

5

Mitte

lwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Bromdichlormethan

DIN 38402 A45

59

6,334 - 10,502 µg/l (|Zu-Score| < 2,00)



12,48% (Limited)

12,48%

1,034 µg/l


1 9,000 0,643 9,000101 7,990 -0,305 7,990102 8,870 0,526 8,870103 8,200 -0,090 8,200107 8,050 -0,244 8,050111 10,940 2,396 10,940114 8,540 0,228 8,540117 8,230 -0,059 8,230123 7,530 -0,776 7,530125 8,980 0,625 8,98013 8,320 0,029 8,320131 8,370 0,074 8,370132 8,600 0,282 8,600134 10,030 1,574 10,030136 9,170 0,797 9,170137 9,391 0,996 9,391138 8,890 0,544 8,890139 8,342 0,049 8,34214 6,320 -2,014 6,320141 6,900 -1,420 6,900142 7,000 -1,318 7,000145 5,950 -2,392 5,950147 8,100 -0,192 8,100149 8,350 0,056 8,350150 7,369 -0,940 7,36917 8,860 0,517 8,86025 6,930 -1,390 6,93026 8,010 -0,285 8,0103 6,770 -1,553 6,77032 7,900 -0,397 7,90037 7,750 -0,551 7,75038 7,719 -0,582 7,7195 7,290 -1,021 7,29058 7,998 -0,297 7,99861 7,100 -1,216 7,10062 7,550 -0,755 7,55063 7,160 -1,154 7,16066 7,630 -0,673 7,63071 8,200 -0,090 8,20076 9,430 1,032 9,43077 7,830 -0,469 7,83079 7,700 -0,602 7,700


8 8,900 0,553 8,90081 7,750 -0,551 7,75084 9,475 1,072 9,47585 8,090 -0,203 8,09086 7,963 -0,333 7,96387 10,600 2,089 10,60088 7,710 -0,591 7,71089 8,000 -0,295 8,00090 9,130 0,761 9,13091 11,390 2,802 11,39092 11,600 2,992 11,60093 7,650 -0,653 7,65094 9,408 1,012 9,40895 9,550 1,140 9,55096 9,470 1,068 9,47097 9,420 1,023 9,42099 8,000 -0,295 8,000



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Dibromchlormethan

DIN 38402 A45

58

7,956 - 12,626 µg/l (|Zu-Score| < 2,00)



11,42% (Limited)

11,42%

1,160 µg/l

ProLab 2009

Labor

137 14 3 63 142

117 25 145 61 86 123

114 5 62 150

141 32 99 66 38 37 93 77 26 89 101

147

107

139

131 13 96 71 58 79 149

125 88 8 17 136 1

132

134 85 103

138

102 90 76 94 95 97 84 87 111 91 92

µg/l

14,514

13,513

12,512

11,511

10,5109,5

98,5

87,5

7

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Dibromchlormethan

DIN 38402 A45

58

7,956 - 12,626 µg/l (|Zu-Score| < 2,00)



11,42% (Limited)

11,42%

1,160 µg/l


1 10,800 0,520 10,800101 9,820 -0,307 9,820102 11,400 1,006 11,400103 11,100 0,763 11,100107 9,870 -0,262 9,870111 13,570 2,764 13,570114 9,180 -0,888 9,180117 8,910 -1,133 8,910123 9,170 -0,897 9,170125 10,400 0,196 10,40013 9,950 -0,189 9,950131 9,920 -0,216 9,920132 10,900 0,601 10,900134 10,910 0,609 10,910136 10,730 0,463 10,730137 2,141 -7,281 2,141138 11,250 0,885 11,250139 9,896 -0,238 9,89614 7,830 -2,114 7,830141 9,400 -0,688 9,400142 8,800 -1,233 8,800145 9,150 -0,915 9,150147 9,830 -0,298 9,830149 10,380 0,180 10,380150 9,389 -0,698 9,38917 10,675 0,419 10,67525 8,990 -1,061 8,99026 9,749 -0,371 9,7493 8,390 -1,606 8,39032 9,400 -0,688 9,40037 9,501 -0,597 9,50138 9,470 -0,625 9,4705 9,300 -0,779 9,30058 10,205 0,038 10,20561 9,160 -0,906 9,16062 9,300 -0,779 9,30063 8,620 -1,397 8,62066 9,410 -0,679 9,41071 10,150 -0,007 10,15076 11,620 1,185 11,62077 9,660 -0,452 9,66079 10,300 0,115 10,300


8 10,600 0,358 10,60084 12,410 1,825 12,41085 11,000 0,682 11,00086 9,167 -0,900 9,16787 13,300 2,546 13,30088 10,400 0,196 10,40089 9,800 -0,325 9,80090 11,490 1,079 11,49091 13,740 2,902 13,74092 14,300 3,356 14,30093 9,550 -0,552 9,55094 11,685 1,237 11,68595 11,760 1,298 11,76096 10,030 -0,116 10,03097 12,000 1,492 12,00099 9,400 -0,688 9,400



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Tetrachlorethen

DIN 38402 A45

57

0,985 - 1,957 µg/l (|Zu-Score| < 2,00)



16,75% (Limited)

16,75%

0,240 µg/l

ProLab 2009

Labor

25 77 14 86 141

150 3

142

145 89 93 101 71 8 61 147 37 38 139 58 123 62 81 88 131 99 5

107 96 26 117

114

132 32 79 97 149 63 13 138

136 95 76 102 87 66 17 111 85 125 84 91 103 94 134 92 137

µg/l

2,6

2,4

2,2

2

1,8

1,6

1,4

1,2

1

0,8

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Tetrachlorethen

DIN 38402 A45

57

0,985 - 1,957 µg/l (|Zu-Score| < 2,00)



16,75% (Limited)

16,75%

0,240 µg/l


101 1,290 -0,632 1,290102 1,600 0,643 1,600103 2,200 2,921 2,200107 1,440 0,035 1,440111 1,692 0,992 1,692114 1,490 0,225 1,490117 1,480 0,187 1,480123 1,370 -0,273 1,370125 1,780 1,326 1,78013 1,560 0,491 1,560131 1,400 -0,138 1,400132 1,500 0,263 1,500134 2,490 4,022 2,490136 1,580 0,567 1,580137 10,685 35,141 10,685138 1,560 0,491 1,560139 1,360 -0,318 1,36014 1,080 -1,574 1,080141 1,150 -1,260 1,150142 1,200 -1,036 1,200145 1,250 -0,811 1,250147 1,340 -0,407 1,340149 1,510 0,301 1,510150 1,189 -1,085 1,18917 1,664 0,886 1,66425 0,990 -1,978 0,99026 1,477 0,176 1,4773 1,190 -1,081 1,19032 1,500 0,263 1,50037 1,344 -0,389 1,34438 1,346 -0,380 1,3465 1,410 -0,093 1,41058 1,365 -0,295 1,36561 1,330 -0,452 1,33062 1,370 -0,273 1,37063 1,530 0,377 1,53066 1,620 0,719 1,62071 1,300 -0,587 1,30076 1,590 0,605 1,59077 1,040 -1,754 1,04079 1,500 0,263 1,5008 1,300 -0,587 1,300


81 1,370 -0,273 1,37084 1,928 1,888 1,92885 1,720 1,098 1,72086 1,134 -1,332 1,13487 1,600 0,643 1,60088 1,370 -0,273 1,37089 1,250 -0,811 1,25091 2,190 2,883 2,19092 2,600 4,440 2,60093 1,270 -0,722 1,27094 2,413 3,730 2,41395 1,580 0,567 1,58096 1,440 0,035 1,44097 1,500 0,263 1,50099 1,400 -0,138 1,400



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Tribrommethan

DIN 38402 A45

59

1,394 - 2,571 µg/l (|Zu-Score| < 2,00)



15,02% (Limited)

15,02%

0,291 µg/l

ProLab 2009

Labor

134 3 87 14 61 142 66 141 81 86 63 123

114

117 88 38 93 32 8

131

147 26 102 85 96 37 25 77 13 5 99 58 71 150 79 101

132

139

107

136

149

137 90 17 103 89 76 84 138 97 95 94 1

145

125

111 91 62 92

µg/l

2,8

2,6

2,4

2,2

2

1,8

1,6

1,4

1,2

1

0,8

Mitt

elwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Tribrommethan

DIN 38402 A45

59

1,394 - 2,571 µg/l (|Zu-Score| < 2,00)



15,02% (Limited)

15,02%

0,291 µg/l


1 2,300 1,143 2,300101 2,000 0,195 2,000102 1,820 -0,435 1,820103 2,200 0,827 2,200107 2,060 0,384 2,060111 2,378 1,389 2,378114 1,690 -0,912 1,690117 1,690 -0,912 1,690123 1,670 -0,986 1,670125 2,310 1,174 2,31013 1,900 -0,141 1,900131 1,810 -0,472 1,810132 2,000 0,195 2,000134 1,010 -3,409 1,010136 2,110 0,542 2,110137 2,177 0,754 2,177138 2,240 0,953 2,240139 2,018 0,251 2,01814 1,520 -1,536 1,520141 1,630 -1,133 1,630142 1,600 -1,243 1,600145 2,300 1,143 2,300147 1,810 -0,472 1,810149 2,170 0,732 2,170150 1,931 -0,027 1,93117 2,198 0,820 2,19825 1,850 -0,325 1,85026 1,814 -0,457 1,8143 1,450 -1,793 1,45032 1,800 -0,508 1,80037 1,837 -0,372 1,83738 1,755 -0,674 1,7555 1,900 -0,141 1,90058 1,909 -0,108 1,90961 1,590 -1,279 1,59062 2,590 2,059 2,59063 1,640 -1,096 1,64066 1,620 -1,169 1,62071 1,930 -0,031 1,93076 2,210 0,858 2,21077 1,860 -0,288 1,86079 1,990 0,163 1,990


8 1,800 -0,508 1,80081 1,630 -1,133 1,63084 2,225 0,906 2,22585 1,820 -0,435 1,82086 1,630 -1,133 1,63087 1,500 -1,610 1,50088 1,710 -0,839 1,71089 2,200 0,827 2,20090 2,180 0,763 2,18091 2,490 1,743 2,49092 2,700 2,407 2,70093 1,780 -0,582 1,78094 2,253 0,994 2,25395 2,250 0,985 2,25096 1,830 -0,398 1,83097 2,240 0,953 2,24099 1,900 -0,141 1,900



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Trichlorethen

DIN 38402 A45

57

0,579 - 1,200 µg/l (|Zu-Score| < 2,00)



17,71% (Limited)

17,71%

0,153 µg/l

ProLab 2009

Labor

142 87 95 3 63 25 26 88 123

141 14 81 77 93 117 71 102 61 147

145 76 97 136 58 38 150 5 8 89 13 139 32 99 86 114

107 37 132

101

131 62 138 66 96 111 79 17 125 84 134

149 85 137

103 91 94 92

µg/l

1,6

1,5

1,4

1,3

1,2

1,1

1

0,9

0,8

0,7

0,6

0,5

0,4

Mitt

elwer

t

Toleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Trichlorethen

DIN 38402 A45

57

0,579 - 1,200 µg/l (|Zu-Score| < 2,00)



17,71% (Limited)

17,71%

0,153 µg/l


101 0,921 0,349 0,921102 0,774 -0,623 0,774103 1,300 2,595 1,300107 0,900 0,225 0,900111 0,988 0,746 0,988114 0,890 0,165 0,890117 0,770 -0,651 0,770123 0,740 -0,863 0,740125 1,030 0,995 1,03013 0,851 -0,079 0,851131 0,930 0,402 0,930132 0,920 0,343 0,920134 1,050 1,113 1,050136 0,815 -0,333 0,815137 1,220 2,121 1,220138 0,960 0,580 0,960139 0,856 -0,043 0,85614 0,750 -0,793 0,750141 0,740 -0,863 0,740142 0,490 -2,631 0,490145 0,800 -0,439 0,800147 0,791 -0,503 0,791149 1,070 1,232 1,070150 0,829 -0,234 0,82917 0,995 0,788 0,99525 0,710 -1,076 0,71026 0,723 -0,986 0,7233 0,630 -1,641 0,63032 0,870 0,047 0,87037 0,908 0,272 0,90838 0,827 -0,248 0,8275 0,850 -0,086 0,85058 0,825 -0,262 0,82561 0,790 -0,510 0,79062 0,940 0,462 0,94063 0,697 -1,168 0,69766 0,970 0,639 0,97071 0,770 -0,651 0,77076 0,810 -0,368 0,81077 0,753 -0,772 0,75379 0,990 0,758 0,9908 0,850 -0,086 0,850


81 0,750 -0,793 0,75084 1,048 1,102 1,04885 1,100 1,410 1,10086 0,877 0,088 0,87787 0,600 -1,854 0,60088 0,730 -0,934 0,73089 0,850 -0,086 0,85091 1,300 2,595 1,30092 1,600 4,373 1,60093 0,758 -0,736 0,75894 1,356 2,927 1,35695 0,610 -1,783 0,61096 0,980 0,699 0,98097 0,810 -0,368 0,81099 0,870 0,047 0,870



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Trichlormethan

DIN 38402 A45

60

0,392 - 0,906 µg/l (|Zu-Score| < 2,00)



20,19% (Limited)

20,19%

0,126 µg/l

ProLab 2009

Labor

3 90 1 77 141

145 87 89 58 131 61 71 86 14 136

117

142

138

147 25 88 93 62 66 26 38 37 107

123 95 13 139

114 5 79 150 32 8 84 63 81 76 101

102

132 96 17 97 85 103

137

149 99 125 94 134 91 111 92 98

µg/l

1,1

1

0,9

0,8

0,7

0,6

0,5

0,4

0,3

0,2

Mitte

lwer

tToleranzgrenze

Toleranzgrenze



Parameter:

Methode:

Anzahl Labore:

Toleranzgrenzen:

Soll-STD:


Rel.Soll STD:


G

Trichlormethan

DIN 38402 A45

60

0,392 - 0,906 µg/l (|Zu-Score| < 2,00)



20,19% (Limited)

20,19%

0,126 µg/l


1 0,440 -1,588 0,440101 0,683 0,421 0,683102 0,692 0,484 0,692103 0,760 0,965 0,760107 0,600 -0,203 0,600111 0,897 1,934 0,897114 0,630 0,046 0,630117 0,550 -0,636 0,550123 0,610 -0,117 0,610125 0,795 1,213 0,79513 0,616 -0,065 0,616131 0,510 -0,982 0,510132 0,700 0,541 0,700134 0,890 1,885 0,890136 0,543 -0,696 0,543137 0,760 0,965 0,760138 0,560 -0,549 0,560139 0,618 -0,048 0,61814 0,540 -0,722 0,540141 0,480 -1,241 0,480142 0,550 -0,636 0,550145 0,500 -1,068 0,500147 0,565 -0,506 0,565149 0,780 1,107 0,780150 0,637 0,096 0,63717 0,739 0,817 0,73925 0,570 -0,463 0,57026 0,593 -0,263 0,5933 0,270 -3,058 0,27032 0,640 0,117 0,64037 0,598 -0,221 0,59838 0,597 -0,229 0,5975 0,630 0,046 0,63058 0,509 -0,991 0,50961 0,520 -0,895 0,52062 0,580 -0,376 0,58063 0,652 0,202 0,65266 0,580 -0,376 0,58071 0,520 -0,895 0,52076 0,680 0,400 0,68077 0,473 -1,302 0,47379 0,630 0,046 0,630


8 0,650 0,187 0,65081 0,660 0,258 0,66084 0,650 0,187 0,65085 0,750 0,895 0,75086 0,522 -0,878 0,52287 0,500 -1,068 0,50088 0,570 -0,463 0,57089 0,500 -1,068 0,50090 0,400 -1,934 0,40091 0,890 1,885 0,89092 0,980 2,521 0,98093 0,570 -0,463 0,57094 0,853 1,623 0,85395 0,613 -0,091 0,61396 0,710 0,612 0,71097 0,740 0,824 0,74098 19,300 132,080 19,30099 0,790 1,178 0,790


Sollwert-Toleranz Diagramm

Parameter: 1,2-Dichlorethan

Rel. Abweichung v om Sollwert Tol. Limit (oben)

Sollw ert1098765432

D B A F E G C

Rel

. Abw

eich

ung(

%)

80706050403020100

-10-20-30-40-50-60-70-80-90

Referenzstelle Trinkwasser FB 61.1



Parameter: Benzol


Sollw ert4321

F A G E D B C

Rel

. Abw

eich

ung(

%)

80706050403020100

-10-20-30-40-50-60-70-80




Parameter: Bromdichlormethan


Sollw ert987654321

E D C F B G A

Rel

. Abw

eich

ung(

%)

60

50

40

30

20

10

0

-10

-20

-30

-40




Parameter: Dibromchlormethan


Sollw ert10987654321

C D E B F A G

Rel

. Abw

eich

ung(

%)

40

30

20

10

0

-10

-20

-30

-40




Parameter: Tetrachlorethen


Sollw ert87654321

A G B D C E F

Rel

. Abw

eich

ung(

%)

60

50

40

30

20

10

0

-10

-20

-30

-40

-50

-60

-70




Parameter: Tribrommethan


Sollw ert987654321

B G C E A D F

Rel

. Abw

eich

ung(

%)

60

50

40

30

20

10

0

-10

-20

-30

-40

-50

-60




Parameter: Trichlorethen


Sollw ert87654321

B G D C A F E

Rel

. Abw

eich

ung(

%)

60

50

40

30

20

10

0

-10

-20

-30

-40

-50




Parameter: Trichlormethan


Sollw ert7654321

G E F A D C B

Rel

. Abw

eich

ung(

%)

50

40

30

20

10

0

-10

-20

-30

-40


Date post:	05-Jun-2018
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Trinkwasser-Ringversuch 4/2009 - LANUV: Home · 4 Die Auswertung der Daten dieses Ringversuchs...

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